Macromolecular Rapid Communications, Vol.30, No.20, 1736-1740, 2009
3-Ethylated N-Vinyl-2-pyrrolidone with LCST Properties in Water
The monomer 3-ethyl-1-vinyl-2-pyrrolidone (3) and the homopolymer poly(3-ethyl-1-vinyl-2-pyrrolidone) (5) have been synthesized. Polymer 5 is soluble in water and shows a critical temperature (T-c) of 27 degrees C. The presence of cyclodextrin causes a slight shift of the T-c. The lower critical solution temperature (LCST) could be varied between 27 and 40 degrees C by copolymerization with N-vinyl-2-pyrrolidone. A linear correlation between the T-c and the copolymer composition is observed.
Keywords:3-ethyl-1-vinyl-2-pyrrolidone;hydrophihc polymers;LCST;stimuli-sensitive polymers;N-vinyl-2-pyrrolidone (NVP)