화학공학소재연구정보센터
Journal of Vacuum Science & Technology B, Vol.26, No.5, 1712-1717, 2008
Correlation of the growth rate for selective epitaxial growth of silicon and oxide thickness and oxide coverage in a reduced pressure chemical vapor deposition pancake reactor
The selective epitaxial growth (SEG) rate of silicon for wafers with various oxide coverages (OCs) (the ratio of oxide area to silicon area on a silicon wafer) and oxide thicknesses, ranging from 0% to 90% and 0 to 500 nm, respectively, in a rf heated cold-wall reduced-pressure chemical vapor deposition (RPCVD) pancake reactor, using the SiH2Cl2-HCl-H-2 gas system, was investigated at a chamber pressure of 40 Torr and a temperature of 970 degrees C. The highest growth rate is about 175 nm/min, occurred at the oxide coverage of 90% and oxide thickness of 200 nm; the lowest growth rate is about 112 nm/min, occurred at the oxide coverage of 30% and oxide thickness of 500 nm. The growth rate of a control sample (a bare silicon wafer) is 110 nm/min. According to these data, a semiempirical expression for the SEG rate of undoped wafers in an RPCVD pancake reactor system is developed. The growth rate is exponentially dependent on the oxide coverage and a function of oxide thickness. This expression is suitable for the in situ p-type doped wafer with 60% OC and the boron concentration of 1.0x10(17) cm(-3) as well. (C) 2008 American Vacuum Society.