The brilliant red [Fe(bpy)(3)](2+) complex upon immobilization on a strongly acidic cation exchanger or in situ formation of the same cationic complex onto a resin matrix and subsequent modified hydrothermolysis (MHT) at similar to 110 degrees C produces unusually stable hierarchical magnetite (Fe3O4) nanowafers. The slow hydrothermolysis, oxidation, and subsequent dehydration of the complex on the solid-liquid interface produce stable hierarchical nanostructures. The isolation of neat Fe3O4 (uncapped) particles from the resin matrix as hierarchical nanowafers was achieved by magnetically stirring a CH3CN suspension of nanocomposites. The solid resin support not only aids nanowafer formation on its surface but also provides unique stability to the magnetite particles, where nanowarer oxidation is largely retarded. The utility of the as-prepared porous nanocomposite and characterization of the nanoparticles are promising for nanotechnological and soft ferromagnetic applications.