The present work aims to study the ageing behaviour of directly quenched Cu-added microalloyed steels. Temperatures related to precipitation of Cu and recovery of dislocations retained in the microstructure after quenching of the steels from finish rolling temperature are determined by differential scanning calorimetric method. Ageing of the directly quenched steels has resulted in the reduction in hardness and strength with concomitant improvement of ductility. 1.5 wt% Cu-added Ti-B microalloyed steel has yielded the most attractive combination of strength and ductility. Presence of Ni in the 1.5 wt% Cu-added Ti-B microalloyed steel indicates sluggish kinetics of Cu precipitation. Ageing has generally deteriorated the impact toughness except for Ni containing Cu-added microalloyed steel above -25 degrees C temperature. Formation of recovered dislocation cells and fine epsilon-Cu precipitates during ageing have contributed to the microstructural softening and hardening, respectively. (C) 2009 Elsevier B.V. All rights reserved.