HPLC를 이용한 석유제품 내의 가시적 식별제 분석

임영관; 김동길; 임의순; 신성철; Young-Kwan Lim; Dong-Kil Kim; Eui Soon Yim; Seong-Cheol Shin

Applied Chemistry for Engineering, Vol.21, No.3, 306-310, June, 2010

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HPLC를 이용한 석유제품 내의 가시적 식별제 분석

Determination of Visible Marker in Petroleum Using HPLC

임영관 ^†, 김동길, 임의순 , 신성철

한국석유관리원 연구센터

Young-Kwan Lim^†, Dong-Kil Kim, Eui Soon Yim , and Seong-Cheol Shin

Research Center, Korea Institute of Petroleum Management, Chungbuk 363-883, Korea

E-mail:

초록

석유제품의 분별 및 유종의 불법혼입방지를 위해 현재 석유제품 내에 일정한 색을 띄는 가시적 식별제(착색제)를 혼입, 유통시키고 있다. 하지만 타유종이 미량 혼입되었을 경우, 육안으로 이를 판별하기 힘들다. 본 연구는 국내에서 사용되고 있는 가시적 식별제를 UV/Vis spectrophotometer를 이용하여, 이들을 분석할 수 있는 두 파장(370 nm, 645 nm)을 찾아내었다. 이렇게 분석된 파장에서 HPLC를 이용해 국내 석유제품 내의 가시적 식별제를 분리, 분석하였다. 또한 정상 석유제품에 타유종을 혼합한 뒤, 가시적 식별제를 분석함으로 석유제품의 불법 혼합판별을 할 수 있는 분석방법을 찾아내었다.

Petroleum visible markers (dye) have been used to distinguish different fuel classes and to prevent illegal mixing. It is difficult to recognize the real color of visible marker when the small amount of petroleum product was mixed in another fuel oil. In this study, we determined the two wavelengths (370 nm, 645 nm) which detect all Korean petroleum visible marker using UV/Vis spectrophotometer. Then we analyzed the visible marker using high performance liquid chromatography (HPLC) in two wavelength detectors. Also, we optimized the analytic method for petroleum visible marker in illegal mixed fuel oil.

Keywords:visible marker;petroleum;dye;HPLC;UV/Vis spectrophotometer

[References]

Suwanprasop S, Nhujak T, Roengsumran S, Petsom A, Ind. Eng. Chem. Res., 43(17), 4973 (2004)
Lee JY, Kim CJ, Yakhak Hoeji, 50, 313 (2006)
Hallisy MJ, United state patent, patent number 5,252,106.
Suwanprasop S, Suksorn S, Nhujak T, Roengsumran S, Petsom A, Ind. Eng. Chem. Res., 42(21), 5054 (2003)
Orelup RB, United state patent, patent number 4,735,631.
Trindade MAG, Zanoni MVB, Matysik FM, Fuel, In Press (2009)
Timkovich R, Dyes Pigm., 46, 69 (2000)
Rostad CE, Fuel, In Press (2009)
Itsei S, Petrotech., 24, 848 (2001)
Notification 2004-345 of Ministry of Maritime Affairs and Fisheries, Supply of free-tax fuel for marine & management guidelines.
Korea Petroleum Quality Inspection Institute, Petroleum and Lubricity, 57, 28 (1998)
Wan PJ, Pakarinen DR, J. American Oil Chem. Soc., 72, 455 (1995)
Okubo SR, Kanawati A, Richards MW, Childress S, J. Prosthet. Dent., 80, 642 (1998)
Chen CC, Wang IJ, Dyes Pigm., 15, 69 (1991)
Lim YK, Kim DK, Yim ES, Shin SC, Korean Chem. Eng. Res., 47(5), 593 (2009)
KPETRO, internal test method, KPETRO-STM-9.

[Referenced By]

[Related Articles]

[1] Suwanprasop S, Nhujak T, Roengsumran S, Petsom A, Ind. Eng. Chem. Res., 43(17), 4973 (2004)

[2] Lee JY, Kim CJ, Yakhak Hoeji, 50, 313 (2006)

[3] Hallisy MJ, United state patent, patent number 5,252,106.

[4] Suwanprasop S, Suksorn S, Nhujak T, Roengsumran S, Petsom A, Ind. Eng. Chem. Res., 42(21), 5054 (2003)

[5] Orelup RB, United state patent, patent number 4,735,631.

[6] Trindade MAG, Zanoni MVB, Matysik FM, Fuel, In Press (2009)

[7] Timkovich R, Dyes Pigm., 46, 69 (2000)

[8] Rostad CE, Fuel, In Press (2009)

[9] Itsei S, Petrotech., 24, 848 (2001)

[10] Notification 2004-345 of Ministry of Maritime Affairs and Fisheries, Supply of free-tax fuel for marine & management guidelines.

[11] Korea Petroleum Quality Inspection Institute, Petroleum and Lubricity, 57, 28 (1998)

[12] Wan PJ, Pakarinen DR, J. American Oil Chem. Soc., 72, 455 (1995)

[13] Okubo SR, Kanawati A, Richards MW, Childress S, J. Prosthet. Dent., 80, 642 (1998)

[14] Chen CC, Wang IJ, Dyes Pigm., 15, 69 (1991)

[15] Lim YK, Kim DK, Yim ES, Shin SC, Korean Chem. Eng. Res., 47(5), 593 (2009)

[16] KPETRO, internal test method, KPETRO-STM-9.