New DPP-containing polyiminoarylenes were prepared from 1,4-diketo-2,5-dihexyl-3,6-di(4'-bromo-phenyl)pyrrolo[3,4-c]pyrrole and various arylamine derivatives using palladium-catalyzed amination reactions. The arylamine comonomers were aniline (ANI), t-butylaniline (TBA). 2-aminoanthracene (AAN), 1-aminopyrene (APY) and N,N'-diphenyl-p-phenylenediamine (PDA). Purple red polymers with good solubility in common organic solvents and molecular weights between 4.4 and 35.8 kDa were obtained. Polymer solutions were readily fluorescent with quantum yields between 19 and 62%, while solution-cast films only showed a weak fluorescence. All polymers exhibit low band gaps of approximately 1.9 eV. Cyclovoltammetric studies indicate quasireversible oxidation for polymers with TBA, APY and PDA as comonomer units, and quasireversible reduction for the polymer with AAN comonomer unit. Polymers with APY and PDA comonomer units are electrochromic and can be switched between red in the neutral and greenish grey in the oxidized state. (C) 2009 Elsevier Ltd. All rights reserved.