Organic-Inorganic Hybrid Nanocomposites of Poly(sodium 4-styrenesulfonate) and Octafunctional Polyhedral Oligomeric Silsesquioxane (POSS)

Jong-Hwan Jeon; Jung-Hyurk Lim; Kyung-Min Kim

Macromolecular Research, Vol.18, No.4, 341-345, April, 2010

DOI10.1007/s13233-010-0414-3 Export Citation

Organic-Inorganic Hybrid Nanocomposites of Poly(sodium 4-styrenesulfonate) and Octafunctional Polyhedral Oligomeric Silsesquioxane (POSS)

Jong-Hwan Jeon, Jung-Hyurk Lim, and Kyung-Min Kim^†

Department of Polymer Science and Engineering, Chungju National University, Chungbuk, 380-702, Korea

E-mail:

The hybrid nanocomposites of poly(sodium 4-styrenesulfonate) (PSS) and octafunctional polyhedral oligomeric silsesquioxane (POSS) (Cube-aminopropyl) were prepared using Cube-aminopropyl as a cross-linker at various weight ratios. Ionic interactions between PSS and Cube-aminopropyl played a critical role in the formation of new hybrid gels with Cube-aminopropyl. The nanocomposites obtained were insoluble in organic or aqueous solvents. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) showed that the hybrid gels were comprised of three-dimensional network structures derived from Cube-aminopropyl as a cross-linker.

Keywords:polyhedral oligomeric silsesquioxane (POSS);ionic interaction;hybrid nanocomposites;cross-linker

[References]

Wen J, Wilkes GL, Chem. Mater., 8, 1667 (1996)
NOVAK BM, Adv. Mater., 5(6), 422 (1993)
Gangopadhyay R, De A, Chem. Mater., 3, 608 (2000)
Han SJ, Shin K, Suh KD, Ryu JH, Macromol. Res., 16(5), 399 (2008)
Lee SM, Shim DC, Lee JW, Macromol. Res., 16(1), 6 (2008)
Tamaki R, Chujo Y, Kuraoka K, Yazawa T, J. Mater. Chem.
Ogoshi T, Itoh H, Kim KM, Chujo Y, Macromolecules, 35(2), 334 (2002)
Kim KM, Keum DK, Chujo Y, Macromolecules, 36(3), 867 (2003)
Schmidt H, Scholze H, Kaiser A, J. Non-Cryst. Solids, 63, 1 (1984)
Brinker CJ, Scherer GW, J. Non-Cryst. Solids, 70, 301 (1985)
Wei Y, Yeh JM, Jin D, Jia X, Wang J, Chem. Mater., 7, 969 (1995)
Wei Y, Yang D, Tang L, Hutchins MK, J. Mater. Res., 8, 1143 (1993)
Chujo Y, Saegusa T, Adv. Polym. Sci., 100, 11 (1992)
Tamaki R, Samura K, Chujo Y, Chem. Commun., 1131 (1998)
Tamaki R, Chujo Y, Chem. Mater., 7, 1719 (1999)
Loy DA, Shea KJ, Chem. Rev., 95(5), 1431 (1995)
Agaskar PA, J. Am. Chem. Soc., 111, 6858 (1989)
Sellinger A, Laine RM, Chem. Mater., 8, 1592 (1996)
Lichtenhan JD, Otonari YA, Carr MJ, Macromolecules, 28(24), 8435 (1995)
Zhang HX, Lee HY, Shin YJ, Lee DH, Noh SK, Macromol. Res., 17(5), 352 (2009)
An YC, Jeon JH, Lee SW, Min BG, Lim JH, Kim KM, Polym. J., 41, 303 (2009)
Kim KM, Adachi K, Chujo Y, Polymer, 43(4), 1171 (2002)
Kim KM, Chujo Y, J. Polym. Sci. A: Polym. Chem., 41(9), 1306 (2003)
Kim KM, Polym.(Korea), 30(5), 380 (2006)
Kim KM, Chujo Y, J. Polym. Sci. A: Polym. Chem., 39(22), 4035 (2001)
Kim KM, Chujo Y, J. Mater. Chem., 13, 1384 (2003)
Kim KM, Lim JH, Jang NY, Kim SR, Macromol. Symp., 249, 562 (2007)
Laine RM, Gravel MC, Polym. Prepr., 38, 155 (1997)
Kim KS, Lee YJ, Lyoo WS, Noh SK, Polym.(Korea), 32(6), 587 (2008)

[Referenced By]

[1] Wen J, Wilkes GL, Chem. Mater., 8, 1667 (1996)

[2] NOVAK BM, Adv. Mater., 5(6), 422 (1993)

[3] Gangopadhyay R, De A, Chem. Mater., 3, 608 (2000)

[4] Han SJ, Shin K, Suh KD, Ryu JH, Macromol. Res., 16(5), 399 (2008)

[5] Lee SM, Shim DC, Lee JW, Macromol. Res., 16(1), 6 (2008)

[6] Tamaki R, Chujo Y, Kuraoka K, Yazawa T, J. Mater. Chem.

[7] Ogoshi T, Itoh H, Kim KM, Chujo Y, Macromolecules, 35(2), 334 (2002)

[8] Kim KM, Keum DK, Chujo Y, Macromolecules, 36(3), 867 (2003)

[9] Schmidt H, Scholze H, Kaiser A, J. Non-Cryst. Solids, 63, 1 (1984)

[10] Brinker CJ, Scherer GW, J. Non-Cryst. Solids, 70, 301 (1985)

[11] Wei Y, Yeh JM, Jin D, Jia X, Wang J, Chem. Mater., 7, 969 (1995)

[12] Wei Y, Yang D, Tang L, Hutchins MK, J. Mater. Res., 8, 1143 (1993)

[13] Chujo Y, Saegusa T, Adv. Polym. Sci., 100, 11 (1992)

[14] Tamaki R, Samura K, Chujo Y, Chem. Commun., 1131 (1998)

[15] Tamaki R, Chujo Y, Chem. Mater., 7, 1719 (1999)

[16] Loy DA, Shea KJ, Chem. Rev., 95(5), 1431 (1995)

[17] Agaskar PA, J. Am. Chem. Soc., 111, 6858 (1989)

[18] Sellinger A, Laine RM, Chem. Mater., 8, 1592 (1996)

[19] Lichtenhan JD, Otonari YA, Carr MJ, Macromolecules, 28(24), 8435 (1995)

[20] Zhang HX, Lee HY, Shin YJ, Lee DH, Noh SK, Macromol. Res., 17(5), 352 (2009)

[21] An YC, Jeon JH, Lee SW, Min BG, Lim JH, Kim KM, Polym. J., 41, 303 (2009)

[22] Kim KM, Adachi K, Chujo Y, Polymer, 43(4), 1171 (2002)

[23] Kim KM, Chujo Y, J. Polym. Sci. A: Polym. Chem., 41(9), 1306 (2003)

[24] Kim KM, Polym.(Korea), 30(5), 380 (2006)

[25] Kim KM, Chujo Y, J. Polym. Sci. A: Polym. Chem., 39(22), 4035 (2001)

[26] Kim KM, Chujo Y, J. Mater. Chem., 13, 1384 (2003)

[27] Kim KM, Lim JH, Jang NY, Kim SR, Macromol. Symp., 249, 562 (2007)

[28] Laine RM, Gravel MC, Polym. Prepr., 38, 155 (1997)

[29] Kim KS, Lee YJ, Lyoo WS, Noh SK, Polym.(Korea), 32(6), 587 (2008)