CaCO3 crystallization with feeding of aspartic acid

Jin-Ho Kim; Sung Moon Song; Jong Min Kim; Woo Sik Kim; In Ho Kim

Korean Journal of Chemical Engineering, Vol.27, No.5, 1532-1537, September, 2010

DOI10.1007/s11814-010-0245-0 Export Citation

CaCO3 crystallization with feeding of aspartic acid

Jin-Ho Kim, Sung Moon Song, Jong Min Kim¹, Woo Sik Kim², and In Ho Kim^†

Department of Chemical Engineering, Chungnam National University, 220, Gung-dong, Yuseong-gu, Daejeon 305-764, Korea
¹Department of Chemical Engineering, Dong A University, 840, Hadan-2dong, Saha-gu, Busan 204-714, Korea
²Department of Chemical Engineering, Kyunghee University, 1, Seocheon-dong, Yongin, Gyunggi-do 446-701, Korea

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Aspartic acid (Asp) was employed as the organic template in inducing the nucleation and growth of calcium carbonate. Crystallization experiments were carried out by the addition of Asp into the solution of sodium carbonate and calcium chloride. The effects of reaction time, dropping velocity of Asp and Na2CO3 solution were tested. The CaCO3 crystals were analyzed by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM) and Fourier transform infrared spectrometry (FT-IR). Two kinds of crystals were identified by FT-IR spectrum. In the presence of Asp, formation of vaterite is induced in crystallization solution. Also, under the initial condition of an excess amount of Asp, vaterite morphology is the major one. Various morphologies of CaCO3 are made by changing dropping velocity of added Asp and Na2CO3.

Keywords:Feeding;Calcium Carbonate;Aspartic Acid

[References]

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Wen Y, Xiang L, Jin Y, Mater. Lett., 57, 2565 (2003)
Kang SH, Hirasawa I, Kim WS, Choi CK, J. Colloid Interface Sci., 288(2), 496 (2005)
Wei H, Shen Q, Zhao Y, Zhou Y, Wang DJ, Xu DF, J. Cryst. Growth, 279(3-4), 439 (2005)
Carteret C, Dandeu A, Moussaoui S, Muhr H, Humbert B, Plasari E, J. Cryst. Growth., 9(2), 807 (2009)
Kim WS, Hirasawa I, Kim WS, Ind. Eng. Chem. Res., 43(11), 2650 (2004)
Wei H, Shen QA, Wang HH, Gao YY, Zhao Y, Xu DF, Wang DJ, J. Cryst. Growth, 303(2), 537 (2007)
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Han YS, Hadiko G, Fuji M, Takahashi M, J. Cryst. Growth, 289(1), 269 (2006)
Han HK, Kim BM, Kim JA, Korean Chem. Eng. Res., 46(6), 1056 (2008)
Hou WT, Feng QL, J. Cryst. Growth, 282(1-2), 214 (2005)
Kontoyannis CG, J. Pharmaceut. Biomed. Anal., 13(1), 73 (1995)
Shivkumara C, Singh P, Gupta A, Hegde MS, Mater. Res.Bull., 41, 1455 (2006)
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Takeuchi T, Sarashina I, Iijima M, Endo K, Febs Lett., 582, 591 (2008)
Jiao Y, Feng Q, Li X, Mater. Sci. Eng. C., 26, 648 (2006)
Manoli F, Kanakis J, Malkaj P, Dalas E, J. Cryst. Growth, 236(1-3), 363 (2002)
Manoli F, Dalas E, J. Cryst. Growth, 222(1-2), 293 (2001)
Xie AJ, Shen YH, Zhang CY, Yuan ZW, Zhu XM, Yang YM, J. Cryst. Growth, 285(3), 436 (2005)
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Wentao H, Qingling F, Mater. Sci. Eng. C., 26, 644 (2006)
Kim JH, Kim JM, Kim WS, Kim IH, Korean Chem. Eng. Res., 47(2), 213 (2009)

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[13] Kontoyannis CG, J. Pharmaceut. Biomed. Anal., 13(1), 73 (1995)

[14] Shivkumara C, Singh P, Gupta A, Hegde MS, Mater. Res.Bull., 41, 1455 (2006)

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[18] Lukeman PS, Stevenson ML, Seeman NC, Cryst. Growth Des., 8(4), 1200 (2008)

[19] Addadi L, Weiner S, NATURE., 411, 753 (2001)

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[22] Manoli F, Kanakis J, Malkaj P, Dalas E, J. Cryst. Growth, 236(1-3), 363 (2002)

[23] Manoli F, Dalas E, J. Cryst. Growth, 222(1-2), 293 (2001)

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[29] Kim JH, Kim JM, Kim WS, Kim IH, Korean Chem. Eng. Res., 47(2), 213 (2009)