화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.16, No.4, 539-545, July, 2010
DOI10.1016/j.jiec.2010.03.026  Export Citation
Catalytic decomposition of dibenzothiophene sulfones over layered double hydroxide catalysts
Min Ji Kim, Hyeonjoo Kim, Kwang-Eun Jeong1, Soon-Yong Jeong1, Young Kwon Park2, and Jong-Ki Jeon†
  • Department of Chemical Engineering, Kongju National University, Cheonan 330-717, Republic of Korea
  • 1Green Chemistry Research Division, Korea Research Institute of Chemical Technology, Daejeon 305-600, Republic of Korea
  • 2School of Environmental Engineering, Department of Urban Environmental System Engineering, University of Seoul, Seoul 130-743, Republic of Korea
E-mail:
The object of the present study is to apply layered double hydroxide catalysts to remove sulfur dioxide from sulfone compounds, by-products of Oxidative Desulfurization (ODS). The effects of Mg/Al ratio, aging temperature, and calcination on the characteristics of the layered double hydroxide catalysts were investigated through the BET surface area, XRD, SEM, and temperature-programmed desorption of CO2. The layered double hydroxide catalyst with an Mg/Al ratio of 2 or 3 and with an aged temperature of 150 ℃ was found to be optimal for the decomposition of dibenzothiophene sulfone. It has since been ascribed to a well-developed LDH structure and has the greatest amount of base site. The optimized layered double hydroxide catalysts were found to have high activity and stability during the catalytic removal of sulfur dioxide from sulfones that were in ODS diesel.
Keywords:Sulfone;Solid base catalyst;Oxidative desulfurization;Mg-Al-LDH
  1. Prasad VVDN, Jeong KE, Chae HJ, Kim CU, Jeong SY, Catal. Commun., 9, 1966 (2008)
  2. Lu L, Cheng SF, Gao JB, Gao GH, He MY, Energy Fuels, 21(1), 383 (2007)
  3. Liu S, Wang B, Cui B, Sun L, Fuel., 87, 422 (2008)
  4. Ishihara A, Wang DH, Dumeignil F, Amano H, Qian EWH, Kabe T, Appl. Catal. A: Gen., 279(1-2), 279 (2005)
  5. Sampanthar JT, Xiao H, Dou H, Nah TY, Rong X, Kwan WP, Appl. Catal. B: Environ., 63(1-2), 85 (2006)
  6. Otsuki S, Nonaka T, Takashima N, Qian WH, Ishihara A, Imai T, Kabe T, Energy Fuels, 14(6), 1232 (2000)
  7. Campos-Martin JM, Capel-Sanchez MC, Fierro JLG, Green Chem., 6, 557 (2004)
  8. Jeong KE, Cho CS, Chae HJ, Kim CU, Jeong SY, J. Nanosci. Nanotechnol., 10, 3547 (2010)
  9. Abdalla ZEA, Li B, Tufail A, J. Ind. Eng. Chem., 15(6), 780 (2009)
  10. Kocal JA, Brandvold TA. Removal of sulfur-containing compounds from liquid hydrocarbon streams, US Patent 6368495 (2002)
  11. You N, Kim MJ, Jeong KE, Jeong SY, Park YK, Jeon JK, J. Nanosci. Nanotechnol., 10, 3663 (2010)
  12. Oviedo A, Torres-Nieto J, Arevalo A, Garcia JJ, J. Mol. Catal. A-Chem., 293(1-2), 65 (2008)
  13. Lee IH, Seol MS, Yoon SJ, J. Ind. Eng. Chem., 11(5), 743 (2005)
  14. Hattori H, Appl. Catal. A: Gen., 222(1-2), 247 (2001)
  15. Lei XD, Zhang FZ, Yang L, Guo XX, Tian YY, Fu SS, Li F, Evans DG, Duan X, AIChE J., 53(4), 932 (2007)
  16. Shumaker JL, Crofcheck C, Tackett SA, Santillan-Jimenez E, Morgan T, Ji Y, Crocker M, Toops TJ, Appl. Catal. B: Environ., 82(1-2), 120 (2008)
  17. Valente JS, Tzompantzi F, Prince J, Cortez JGH, Gomez R, Appl. Catal. B: Environ., 90(3-4), 330 (2009)
  18. Manivannan R, Pandurangan A, Appl. Clay Sci., 44, 137 (2009)
  19. Winter F, Wolters M, van Dillen AJ, de Jong KP, Appl. Catal. A: Gen., 307(2), 231 (2006)
  20. Gao L, Teng G, Lv J, Xiao G, Energy Fuel, doi:10.1021/ef900800d, in press.
  21. Yang JI, Kim JN, Korean J. Chem. Eng., 23(1), 77 (2006)
  22. Prinetto F, Ghiotti G, Durand R, Tichit D, J. Phys. Chem. B, 104(47), 11117 (2000)
  23. Parida K, Das J, J. Mol. Catal. A-Chem., 151(1-2), 185 (2000)
  24. Di Cosimo JI, Dı´ez VK, Apesteguı´a CR, Appl. Clay Sci., 13, 433 (1998)
  25. Be´ res A, Pa´ linko´ I , Kiricsi I, React. Kinet. Catal. Lett., 59, 47 (1996)
  26. Constantino VR, Pinnavaia TJ, Catal. Lett., 23(3-4), 361 (1994)
  27. Kang MR, Lim HM, Lee SC, Lee SH, Kim KJ, J. Mater. Online., 6, 218 (2004)
  28. Hattori H, Chem. Rev., 95(3), 537 (1995)
  29. Umdu ES, Tuncer M, Seker E, Bioresour. Technol., 100, 2828 (2009)
  30. Liu S, Zhang X, Li J, Zhao N, Wei W, Sun Y, Catal. Commun., 9, 1527 (2008)
  31. Park YK, Kim SY, Kim HJ, Jung KY, Jeong KE, Jeong SY, Jeon JK, Korean J. Chem. Eng., 27(2), 459 (2010)
  32. Okada K, Kaneda A, Kameshima Y, Yasumori A, Mater. Res. Bull., 37(2), 209 (2002)