화학공학소재연구정보센터
Rheologica Acta, Vol.47, No.9, 999-1013, 2008
Shear and elongational flow behavior of acrylic thickener solutions Part I: Effect of intermolecular aggregation
We investigate the effect of hydrophobic aggregation in alkali-swellable acrylic thickener solutions on shear and extensional flow properties at technically relevant polymer concentrations using the commercial thickener Sterocoll FD as model system. Apparent molecular weight of aggregates in water is M-w approximate to 10(8) g/mol and decreases by more than an order of magnitude in ethanol. Zero shear viscosity eta(0) is low and shear thinning is weak compared to the high molecular weight of the aggregates. Linear viscoelastic relaxation is described by the Zimm theory up to frequencies of 10(4) rad/s, demonstrating that no entanglements are present in these solutions. This is further supported by the concentration dependence of eta(0) and is attributed to strong association within the aggregates. Extensional flow behavior is characterized using the capillary break-up extensional rheometry technique including highspeed imaging. Solutions with phi >= 1% undergo uniform deformation and show pronounced strain hardening up to large Hencky strains. Elongational relaxation times are more than one order of magnitude lower than the longest shear relaxation times, suggesting that aggregates cannot withstand strong flows and do not contribute to the elongational viscosity.