화학공학소재연구정보센터
Rheologica Acta, Vol.48, No.8, 883-895, 2009
Reducing shear thickening of cement-based suspensions
Rheological measurements were made on concrete and mortars to characterize the shear thickening behavior of certain concrete mix designs. Shear thickening reduction levers were found by selecting and designing admixtures. Since the shear-thickening phenomena occur at the scale of the finest particles, industrial limestone fillers were studied that behave like cementitious materials. Theories based on previous academic works were relevant. The shear stress-dependent effects of shear thickening and size scaling were very helpful to distinguish between surface interactions, such as lubrication and volumetric contributions and also including the packing effects. The suspension viscosity curves vary accordingly to the Newtonian viscosity of the solvent medium. In both the shear thinning and shear thickening regimes, viscosity is controlled by adjusting the amount of two specific admixtures. The reduction of friction between polymer-coated materials appears to be a key phenomenon to delay onset shear thickening in industrial processes.