화학공학소재연구정보센터
Solid State Ionics, Vol.180, No.1, 18-21, 2009
Interconnection of the parameters obtained from thermally stimulated depolarization currents in beta- PbF2 doped with rare Earth ions
Earlier measurements of thermally stimulated depolarization currents in cubic PbF2 containing small rare earth ions have led to the determination of the pre-exponential factor tau(0) and the activation energy E involved in the Arrhenius relation tau=tau(0)exp(E/kT). Here, we show that these parameters are interconnected in a way governed by bulk properties. This corroborates with a very recent finding (Solid State Ionics, 179 (2008) 438) which showed that, for various defect processes, the ratio of the activation volume over the corresponding energy is also equal to a bulk quantity. (C) 2008 Elsevier B.V. All rights reserved.