Resistance to oxidation is a major point in catalysis processes when it comes to the properties of catalyst supports that are exposed to harsh conditions such as high temperature and non-negligible concentration of oxidative agents. Indeed, consistent oxidation often leads to the destruction of the support and loss of the catalyst material. Silicon carbide (SiC) has already proved to be very resistant to oxidation below 700 degrees C, but some applications (such as steam methane reforming) require higher oxidative resistance. In this work, we report the synthesis of a new SIC composite made of a beta-SiC host structure covered with SiC nanofibres which exhibits a significant improved oxidative resistance. Such increase of the oxidative resistance was explained by a defect-site inhibition mechanism induced by the presence of SiC nanofibres that was checked with and without the presence of an oxidative catalyst. Crown Copyright (c) 2010 Published by Elsevier B.V. All rights reserved.