화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.27, No.6, 1887-1891, November, 2010
DOI10.1007/s11814-010-0293-5  Export Citation
High pressure isothermal vapor-liquid equilibria for the binary system of carbon dioxide (CO2)+1,1,1-trifluoroethane (R-143a)
Seol A Kim, Ki-Pung Yoo, and Jong Sung Lim†
  • Department of Chemical and Biomolecular Engineering, Sogang University, C.P.O. Box 1142, Seoul 100-611, Korea
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Isothermal vapor-liquid equilibrium data for the binary mixture of carbon dioxide (CO2)+1,1,1-trifluoroethane (HFC-143a) were measured within the temperature range of 273.15-333.15 K. The data in the two-phase region were measured by using a circulation-type equilibrium apparatus in which both vapor and liquid phases are continuously recirculated. The experimental data were correlated with the Peng-Robinson equation of state (PR-EOS) using the Wong-Sandler mixing rules combined with the NRTL excess Gibbs free energy model. The values calculated by the PR EOS with the W-S mixing rules show good agreement with our experimental data.
Keywords:Carbon Dioxide (CO2);HFC-143a;Vapor-liquid Equilibria (VLE);Peng-Robinson Equation of State (PR EOS)
  1. Higashi Y, Ikeda T, Fluid Phase Equilib., 125(1-2), 139 (1996)
  2. Lim JS, Park JY, Lee BG, Korean J. Chem. Eng., 22(6), 932 (2005)
  3. Yun Y, Im J, Shin MS, Lee YW, Kim H, Fluid Phase Equilib., 271(1-2), 34 (2008)
  4. Proba AP, Will S, Leipertz A, Int. J. Refrigeration, 24, 734 (2001)
  5. Madani H, Valtz A, Coquelet C, Meniai AH, Richon D, J. Chem. Thermodyn., 40(10), 1490 (2008)
  6. Lim JS, Jin JM, Yoo KP, J. Supercrit. Fluids, 44(3), 279 (2008)
  7. Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
  8. Wong DSH, Sandler SI, AIChE J., 38, 671 (1992)
  9. Lee BG, Yang WJ, Kim JD, Lim JS, J. Chem. Eng. Data, 48, 841 (2003)
  10. Lim JS, Park JY, Lee KS, Kim JD, Lee BG, J. Chem. Eng. Data, 49, 750 (2004)
  11. Lim JS, Park JY, Kang JW, Lee BG, Fluid Phase Equilib., 243(1-2), 57 (2006)
  12. Lim JS, Seong G, Roh HK, Lee BG, J. Chem. Eng. Data, 52, 2250 (2007)
  13. Wong DSH, Orbey H, Sandler SI, Ind. Eng. Chem. Res., 31, 2033 (1992)
  14. Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)
  15. McLinden MO, Klein SA, Lemmoon EW, Peskin AP, Thermodynamic Properties of Refrigerants and Refrigerant Mixtures Database (REFPROP), V.6.01, NIST (1998)