Polyvinyl alcohol (PVA) and polyvinylpyrrolidone (PVP) were used to prepare polymeric matrix composites of nanohydroxyapatite (HAV and HAP), respectively, by using a biomimetic approach under 100 degrees C. A comparison with synthetic nanohydroxyapatite prepared by precipitation (SHA) was evaluated. Characterization of the prepared powders by differential thermal analysis (DTA) and thermogravimetric analysis (TGA) was achieved, X-ray diffraction (XRD), scanning electron microscope (SEM) with elemental analysis by (EDS) and inductively coupled plasma-optical emission spectrometer were used. DTA and TG showed the weight loss in the 400-1200 degrees C was almost attributed to carbonate decomposition which appeared apparently in the polymer associated samples due to the decomposition of polymer matrix. X-ray diffraction confirmed mainly the formation of hydroxyapatite. Specific surface area (BET) and scanning electron microscope and scanning electron microscopy (SEM) confirmed the range of nanosized of the prepared HA samples. The polymer matrix prefers orientation of the particles to rod-like shape. Elemental analysis showed mainly, Ca, P, C and O ions besides Na and Cl. Inductively coupled plasma showed the composition and the Ca/P atomic ratio of all samples ranging between 1.72 and 1.85. (C) 2009 Elsevier B.V. All rights reserved.