A PREDICTION OF THE ABNORMAL BEHAVIOR IN THE VISCOSITY OF LIQUID WATER UNDER PRESSURE

Kim W; Chair TS

Korean Journal of Chemical Engineering, Vol.10, No.2, 124-126, April, 1993

A phenomenological theory of viscosity proposed by authors was applied to liquid water under high pressure. Thermodynamic properties used in the calculation were obtained by using the theory of liquid proposed by Pak[13]. The calculated viscosities decreased abnormally with increasing pressure. We found this behavior was due to the decrease of the absolute value of kinetic and internal pressure with the pressure increase near 273.15 K.

[References]

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[1] Bridgman PW, Proc. Am. Acad. Arts Sci., 61, 57 (1926)

[2] Tammann G, Rabe H, Z. Allgem. Chem., 168, 73 (1927)

[3] Bett KE, Cappi JB, Nature, 207, 602 (1965)

[4] Webber W, Z. Angew. Phys., 15, 342 (1963)

[5] Einstein A, Ann. Physik., 19, 289 (1906)

[6] Jhon MS, Grosh J, Ree T, Eyring H, J. Chem. Phys., 44, 1486 (1966)

[7] Eyring H, Jhon MS, Chemistry, 39, 12 (1966)

[8] Chair TS, Kim W, Pak H, Jhon MS, Korean J. Chem. Eng., 6(2), 121 (1989)

[9] Kim W, Bull. Korean Chem. Soc., 9, 213 (1988)

[10] Kim W, Pak H, Chair TS, Bull. Korean Chem. Soc., 10, 372 (1989)

[11] Kim W, Pak H, Chair TS, Bull. Korean Chem. Soc., 11, 28 (1990)

[12] Kim W, Chair TS, Bull. Korean Chem. Soc., 11, 446 (1990)

[13] Pak H, Korean Chem. Soc., 20, 460 (1976)

[14] Horne RA, Johnson DS, J. Phys. Chem., 70, 2182 (1966)

[15] Kerr EC, Taylor RD, Ann. Phys., 26, 292 (1964)

[16] Rowlinson JS, Swinton FL, "Liquid and Liquid Mixture," 3rd ed., Butterworth Scientific, London, 46 (1982)