THE KINETICS OF PYRIDINE FORMATION FROM TETRAHYDROFURFURYL ALCOHOL OVER Pd/ -Al<SUB>2</SUB>O<SUB>3</SUB>

Choi JH; Kim HD; Lee WY

Korean Journal of Chemical Engineering, Vol.10, No.3, 135-139, July, 1993

THE KINETICS OF PYRIDINE FORMATION FROM TETRAHYDROFURFURYL ALCOHOL OVER Pd/ -Al₂O₃

A kinetic study of pyridine formation from tetrahydrofurfuryl alcohol over Pd/ -Al₂O₃ was carried out in a differential flow reactor. The best expression for the main reaction was deter-mined from the experimental data. The rate was governed by the irreversible surface reaction between the dissociatively adsorbed ammonia on the hydrogenated surface and molecularly adsorbed tetrahydrofurfuryl alcohol.

[References]

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Bashkirov AN, Kliger GA, Lesik OA, Marchevskaya EV, Glebov LS, Kinet. Catal., 24(2), 392 (1983)
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Choi JH, Lee WY, Appl. Catal., 87(2), 157 (1992)
Choi JH, Lee WY, Appl. Catal., 98, 21 (1993)

[1] Kline CH, Turkevich J, J. Am. Chem. Soc., 66, 1710 (1944)

[2] Manly DG, Halloran JP, Rice FJ, U.S. Patent, 3,163,652 (1964)

[3] Bashkirov AN, Kliger GA, Lesik OA, Marchevskaya EV, Glebov LS, Kinet. Catal., 24(2), 392 (1983)

[4] Manly DG, Barrington JP, O'Halloran CFJ, Rice J, U.S. Patent, 3,238,214 (1966)

[5] Choi JH, Lee WY, Sung BP, HWAHAK KONGHAK, 26(6), 649 (1988)

[6] Butler JD, Laundon RD, J. Chem. Soc., 713 (1969)

[7] Butler JD, Laundon RD, J. Chem. Soc., 716 (1970)

[8] Butler JD, Laundon RD, J. Chem. Soc., 1525 (1970)

[9] Choi JH, Lee WY, Appl. Catal., 87(2), 157 (1992)

[10] Choi JH, Lee WY, Appl. Catal., 98, 21 (1993)