A study of the photocatalytic destruction of propylene using microwave discharge electrodeless lamp

Yeong-Seon Bae; Sang-Chul Jung

Journal of Industrial and Engineering Chemistry, Vol.16, No.6, 947-951, November, 2010

DOI10.1016/j.jiec.2010.05.015 Export Citation

A study of the photocatalytic destruction of propylene using microwave discharge electrodeless lamp

Yeong-Seon Bae, and Sang-Chul Jung^†

Dept. of Environmental Engineering, Sunchon National University, Jeonnam 540-742, Republic of Korea

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A microwave discharge electrodeless lamp (MDEL) was used as the light source for microwave-assisted TiO2 photo-catalysis to degrade propylene. A MDEL filled with low pressure mercury gas has been developed for the photocatalytic treatment of air pollutants over TiO2 balls. TiO2 balls used were produced by the low pressure metal organic chemical vapor deposition method. With increasing microwave power, the degradation efficiency of propylene increased resulting in increased production of CO2, H2O, and CO. It is proposed that propylene is degraded by MDEL and photocatalysts into CH4 and C2H6, which are then mineralized into CO2, H2O, and CO. C2H2 is suggested to be produced from CH4 or C2H6 by microwave.

Keywords:Propylene;Microwave;Electrodeless lamp;TiO2;Chemical vapor deposition

[References]

Glaze WH, Kang JW, Chapin DH, J. AWWA., 80, 57 (1988)
Hoffmann MR, Martin ST, Choi WY, Bahnemann DW, Chem. Rev., 95(1), 69 (1995)
Zanoni MVB, Sene JJ, Anderson MA, J. Photochem. Photobiol. A: Chem., 157, 55 (2003)
Quan X, Chen S, Su J, Chen JW, Chen GH, Sep. Purif. Technol., 34(1-3), 73 (2004)
Matthews RW, Water Res., 20, 569 (1986)
Venkatachalam N, Palanichamy M, Murugesan V, Mater. Chem. Phys., 104(2-3), 454 (2007)
Dorjpalam E, Takahashi M, Tokuda Y, Yoko T, Thin Solid Films, 483(1-2), 147 (2005)
Hitchman M, Tian F, J. Electroanal. Chem., 165, 538 (2002)
Jung SC, Kim BH, Kim SJ, Maishi N, Cho YI, Chem. Vap. Deposition., 11, 137 (2005)
Jung SC, Kim SJ, Imaishi N, Cho YI, Appl. Catal. B: Environ., 55(4), 253 (2005)
Ha JW, Do YW, Park JH, Han CH, J. Ind. Eng. Chem., 15, 607 (2009)
Stadler A, Kappe COJ, Comb. Chem., 3, 624 (2001)
Giguere RJ, Bray TL, Duncan SM, Majetich G, Tetrahedron Lett., 27, 4945 (1986)
Gedye R, Smith F, Westaway K, Ali H, Baldisera L, Laberge L, Rousell J, Tetrahedron Lett., 27, 279 (1986)
Wada Y, Hengbo Y, Yanagida S, Catal. Surv. Jpn., 5, 127 (2002)
Horikoshi S, Hidaka H, Serpone N, J.Photochem.Photobiol.A:Chem., 159, 289 (2003)
Kim SC, Erickson LE, Yu EY, J. Hazard. Mater., 41, 327 (1995)
Kim SC, Kim SJ, Yu EY, Appl. Catal. A: Gen., 150(1), 63 (1997)

[Referenced By]

[1] Glaze WH, Kang JW, Chapin DH, J. AWWA., 80, 57 (1988)

[2] Hoffmann MR, Martin ST, Choi WY, Bahnemann DW, Chem. Rev., 95(1), 69 (1995)

[3] Zanoni MVB, Sene JJ, Anderson MA, J. Photochem. Photobiol. A: Chem., 157, 55 (2003)

[4] Quan X, Chen S, Su J, Chen JW, Chen GH, Sep. Purif. Technol., 34(1-3), 73 (2004)

[5] Matthews RW, Water Res., 20, 569 (1986)

[6] Venkatachalam N, Palanichamy M, Murugesan V, Mater. Chem. Phys., 104(2-3), 454 (2007)

[7] Dorjpalam E, Takahashi M, Tokuda Y, Yoko T, Thin Solid Films, 483(1-2), 147 (2005)

[8] Hitchman M, Tian F, J. Electroanal. Chem., 165, 538 (2002)

[9] Jung SC, Kim BH, Kim SJ, Maishi N, Cho YI, Chem. Vap. Deposition., 11, 137 (2005)

[10] Jung SC, Kim SJ, Imaishi N, Cho YI, Appl. Catal. B: Environ., 55(4), 253 (2005)

[11] Ha JW, Do YW, Park JH, Han CH, J. Ind. Eng. Chem., 15, 607 (2009)

[12] Stadler A, Kappe COJ, Comb. Chem., 3, 624 (2001)

[13] Giguere RJ, Bray TL, Duncan SM, Majetich G, Tetrahedron Lett., 27, 4945 (1986)

[14] Gedye R, Smith F, Westaway K, Ali H, Baldisera L, Laberge L, Rousell J, Tetrahedron Lett., 27, 279 (1986)

[15] Wada Y, Hengbo Y, Yanagida S, Catal. Surv. Jpn., 5, 127 (2002)

[16] Horikoshi S, Hidaka H, Serpone N, J.Photochem.Photobiol.A:Chem., 159, 289 (2003)

[17] Kim SC, Erickson LE, Yu EY, J. Hazard. Mater., 41, 327 (1995)

[18] Kim SC, Kim SJ, Yu EY, Appl. Catal. A: Gen., 150(1), 63 (1997)