The impact of fractional hydrogen preconversion on the subsequent homogeneous ignition characteristics of fuel-lean (equivalence ratio phi = 0.30) H-2/O-2/N-2/CO2 mixtures over platinum was investigated experimentally and numerically at pressures of 1, 5 and 8 bar. Experiments were performed in an optically accessible channel-flow reactor and involved Raman measurements of major species over the catalyst boundary layer and planar laser induced fluorescence (LIF) of the OH radical. Simulations were carried out with a 2-D elliptic code that included detailed hetero-/homogeneous chemistry. The predictions reproduced the LIF-measured onset of homogeneous ignition and the Raman-measured transport-limited catalytic hydrogen consumption. For 0% preconversion and wall temperatures in the range 900 K <= T-w <= 1100 K, homogeneous ignition was largely suppressed for p >= 5 bar due to the combined effects of intrinsic gas-phase hydrogen kinetics and the competition between the catalytic and gas-phase pathways for fuel consumption. A moderate increase of preconversion to 30% restored homogeneous combustion for p >= 5 bar, despite the fact that the water formed due to the upstream preconversion inhibited homogeneous ignition. The catalytically-produced water inhibited gas-phase combustion, particularly at higher pressures, and this kinetic inhibition was exacerbated by the diffusional imbalance of hydrogen that led to over-stoichiometric amounts of water in the near-wall hot ignitable regions. Radical adsorption/desorption reactions hindered the onset of homogeneous ignition and this effect was more pronounced at 1 bar. On the other hand, over the post-ignition reactor length, radical adsorption/desorption reactions significantly suppressed gas-phase combustion at 5 and 8 bar while their impact at 1 bar was weaker. By increasing hydrogen preconversion, the attained superadiabatic surface temperatures could be effectively suppressed. An inverse catalytically stabilized thermal combustion (CST) concept has been proposed, with gas-phase ignition achieved in an upstream porous burner via radiative and heat conduction feedback from a follow-up catalytic reactor. This arrangement moderated the superadiabatic surface temperatures and required modest or no preheat of the incoming mixture. (C) 2010 The Combustion Institute. Published by Elsevier Inc. All rights reserved.