Industrial & Engineering Chemistry Research, Vol.37, No.12, 4617-4624, 1998
Biomass gasification with air in fluidized bed: Reforming of the gas composition with commercial steam reforming catalysts
Four commercial catalysts for steam reforming of higher hydrocarbons (naphthas) and three for steam reforming of light hydrocarbons are tested for hot gas clean up and upgrading in biomass gasification with air in fluidized bed. The catalysts used originate from four manufacturers: BASF AG, ICI-Katalco, Haldor Topsoe a/s, and United Catalysts Inc. The work is performed in a small pilot plant (1-2 kg of biomass fed/h) with three reactors in series: gasifier, guard bed of dolomite, and full flow catalytic bed. Samples of gas are taken before and after the catalytic bed at different times-on-stream. It is shown how the H-2, CO, CO2, CH4 and steam contents in the flue gas change because of the catalytic bed approaching contents near to the ones corresponding to the equilibrium state. Variations in the heating value of the gas and gas yield as a result of the catalytic bed are also reported.