Poly (3,3-dimethyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine), PProDOT-Me-2, is one of the most promising conducting polymers in the alkylenedioxythiophene based family for electrochromic window applications. In the electropolymerization kinetic study of 3,3-dimethyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine (ProDOT-Me-2), microgravimetry and chronoamperometry were used to determine the reaction orders with respect to the electrolyte and monomer, and the corresponding general kinetic equation of electropolymerization. This study presents that monomer concentration has a strong impact on electropolymerization mechanism. The relationship between film thickness and polymerization time was analyzed indicating that saturation of polymerization reduced the increase rate of film thickness with polymerization time. Also, the electropolymerization conditions were optimized to reach high contrast (Delta%T > 70%) with the minimum of transmittance (%T-min < 1) for electrochromic window applications. (C) 2010 Elsevier Ltd. All rights reserved.