Direct conversion of cellulose into polyols or H2 over Pt/Na(H)-ZSM-5

Su Jin You; In Gu Baek; Yong Tae Kim; Kwang-Eun Jeong; Ho-Jeong Chae; Tae-Wan Kim; Chul-Ung Kim; Soon-Yong Jeong; Tae Jin Kim; Young-Min Chung; Seung-Hoon Oh; Eun Duck Park

Korean Journal of Chemical Engineering, Vol.28, No.3, 744-750, March, 2011

DOI10.1007/s11814-011-0019-3 Export Citation

Direct conversion of cellulose into polyols or H2 over Pt/Na(H)-ZSM-5

Su Jin You, In Gu Baek, Yong Tae Kim, Kwang-Eun Jeong¹, Ho-Jeong Chae¹, Tae-Wan Kim¹, Chul-Ung Kim¹, Soon-Yong Jeong¹, Tae Jin Kim², Young-Min Chung², Seung-Hoon Oh², and Eun Duck Park^†

Division of Energy Systems Research and Division of Chemical Engineering and Materials Engineering, Ajou University, San 5 Woncheon-dong, Yeongtong-gu, Suwon 443-749, Korea
¹Korea Research Institute of Chemical Technology, Sinseongno 19, Yuseong-gu, Daejeon 305-600, Korea
²SK Energy Institute of Technology, Wonchon-dong, Yuseong-gu, Daejeon 305-712, Korea

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The direct conversion of cellulose into polyols such as ethylene glycol and propylene glycol was examined over Pt catalysts supported on H-ZSM-5 with different SiO2/Al2O3 molar ratios. The Pt dispersion, determined by CO chemisorption and transmission electron microscopy (TEM), as well as the surface acid concentration measured by the temperature-programmed desorption of ammonia (NH3-TPD), increased with decreasing SiO2/Al2O3 molar ratio for Pt/H-ZSM-5. The total yield of the polyols, i.e., sorbitol, manitol, ethylene glycol and propylene glycol, generally increased with increasing Pt dispersion in Pt/H-ZSM-5. The one-pot aqueous-phase reforming of cellulose into H2 was also examined over the same catalysts. The Pt catalyst supported on H-ZSM-5 with a moderate SiO2/Al2O3 molar ratio and a large external surface area showed the highest H2 production rate. The Pt dispersion, surface acidity, external surface area and surface hydrophilicity appear to affect the catalytic activity for this reaction.

Keywords:Cellulose;Propylene Glycol;Aqueous-phase Reforming;H2;Pt/H-ZSM-5

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Sasaki M, Fang Z, Fukushima Y, Adschiri T, Arai K, Ind. Eng. Chem. Res., 39(8), 2883 (2000)
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