The solubility of calcium sulfate dihydrate (CaSO4 center dot 2H(2)O) and calcium hydroxide (Ca(OH)(2)) in alkali solutions is essential to understand their desilication behavior from Bayer liquor. In this work, solubilities of calcium sulfate dihydrate and calcium hydroxide for the ternary systems of CaSO4 center dot 2H(2)O-NaOH-H2O, CaSO4 center dot 2H(2)O-KOH-H2O, and Ca(OH)(2)-NaOH-H2O were measured by using the classic isothermal dissolution method over the temperature range of 25-75 degrees C. The Pitzer model embedded in Aspen Plus platform was used to model the experimental solubility data for these systems. The experimental solubility data was employed to obtain the new binary interaction parameters for Ca(OH)(+)-OH-, Ca(OH)(+)-Ca2+ and Ca(OH)(+)-K+, suggesting that the species Ca(OH)(+) is a dominant species in simulated solubility for alkali systems. Validation of the parameters was performed by predicting the solubility for the ternary systems of Ca(OH)(2)-NaOH-H2O, CaSO4 center dot 2H(2)O-NaOH-H2O and CaSO4 center dot 2H(2)O-KOH-H2O with the overall average relatively deviation (ARD) of 2.12%, 0.75% and 1.63%, respectively. (C) 2010 Elsevier B.V. All rights reserved.