화학공학소재연구정보센터
Fluid Phase Equilibria, Vol.299, No.1, 60-64, 2010
Experimental and predicted excess molar enthalpies of binary mixtures containing 2,2'-oxybis[propane], benzene, butan-1-ol, 2-methylpropan-1-ol, 2-methy1-2-ene-1-propanol at 303.15 K
Excess molar enthalpies H-E have been measured for liquid binary mixtures of 2,2'-oxybis[propane] (diisopropylether 'DIPE'), or, benzene + butan-1-ol, +2-methylpropan-1-ol (isobutanol), +2-methyl-2-ene-1-propanol (isobutenol), +n-heptane at 303.15 K and constant pressure using a C80, Setaram calorimeter. A Redlich-Kister type equation was used to correlate experimental results. These experimental results, along with our previous data on H-E of DIPE + benzene, +cyclohexane [1] are used for estimating interaction parameters in DISQUAC, an extended quasi-chemical group contribution model [2,3]. (C) 2010 Elsevier B.V. All rights reserved.