A general formulation is presented for a moving boundary problem in which heat is generated at the boundary due to an exothermic reaction involving a species which diffuses into a dispersed phase from an external medium of finite volume. The speed of the moving boundary is prescribed based on the solution of the mass diffusion problem and an analysis is presented of the thermal dynamics of the system. The set of equations describing heat transport leads to a Green's function type problem with time dependent boundary conditions and the Galerkin finite element method is employed to develop a numerical solution. Transformations are introduced to freeze the moving boundary and partition the domain for ease of computation, and an iterative scheme is defined to satisfy the heat flux jump boundary condition and match the temperature field across the moving boundary. The numerical results are used to set the limits of applicability of an analytical perturbation solution. Essential aspects of thermal dynamics in the system are described and parametric regions resulting in a local temperature hot spot are delineated. Computed contour plots describing thermal evolution are presented for different combinations of parameter values. These may be of utility in the prediction of thermal development, for control and avoidance of hot spot formation, and in physical parameter estimation. (C) 2010 Elsevier Ltd. All rights reserved.