Poly ether ether ketone (PEEK) polymer was extruded into filaments and cowoven into unidirectional hybrid fabric with glass as reinforcement fiber. The hybrid fabrics were then converted into laminates and their properties with special reference to crystallization behavior has been studied. The composite laminates have been evaluated for mechanical properties, such as tensile strength, interlaminar shear strength (ILSS), and flexural strength. The thermal behavior of the composite laminates were analyzed using differential scanning calorimeter, thermogravimetric analyzer, dynamic mechanical analyzer (DMA), and thermomechanical analyzer (TMA). The exposure of the fabricated composite laminates to high temperature (400 and 500 degrees C) using radiant heat source resulted in an improvement in the crystallanity. The morphological behavior and PEEK resin distribution in the composite laminates were confirmed using scanning electron microscope (SEM) and nondestructive testing (NDT). Although DMA results showed a loss in modulus above glass transition temperature (T-g), a fair retention in properties was noticed up to 300 degrees C. The ability of the composite laminates to undergo positive thermal expansion as confirmed through TMA suggests the potential application of glass PEEK composites in aerospace sector. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 117: 1446-1459, 2010