Block copolymerization of plural types of monomers offers a new opportunity for the preparation of a variety of multifunctional polymers. Poly(4-diphenylaminostyrene) (PDAS)-poly(9-vinylanthracene) (PVAN) binary block copolymer (PDAS-PVAN) was synthesized by (living) anionic polymerization using the benzyllithium/N,N,N',N'-tetramethylethylenediamine system. The photoluminescence emission of PDAS-PVAN was enhanced by the fluorescence resonance energy transfer from PDAS block to PVAN block in PDAS-PVAN. The hole drift mobility of the copolymer was controllable by the amount of triphenylamino groups in the polymer chain. The optical and electrical properties of PDAS-PVAN were adjustable through the polymer chain structure. (c) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 118: 69-73, 2010