Korean Journal of Chemical Engineering, Vol.13, No.1, 88-96, January, 1996
EXPERIMENTAL STUDY AND MODEL SIMULATION OF A TWO-STAGE CONTINUOUS POLYMERIZATION PROCESS FOR POLYSTYRENE
Free radical solution polymerization of styrene in two stage polymerization process has been studied using a binary mixture of symmetrical bifunctional initiators. The continuous reactor system was composed of two reactor units; a prepolymerization reactor(e.g. stirred tank reactors)and a filled tubular reactor packed with static mixers. When the stirred tank reactor was used as a prepolymerizer, a feed stream to the filled tubular reactor was more viscous than the monomer/solvent mixture. It was of interest to investigate how the performance of the filled tubular reactor has been investigated by the feed of viscous prepolymer solution. A dynamic model of the continuous two stage polymerization process was presented by experimental data and model simulation. A reasonably good agreement between the model and the experimental data was obtained without using any adjustable parameters. The experimental results of the two stage polymerization were compared with the results without prepolymerization reactor. It was found that the addition of a prepolymerization reactor has almost no effect on the performance of the filled tubular reactor.
- ATOCHEM, Technical Bulletin, Buffalo, NY (1986)
- Brandrup J, Immergut EH, Polymer Handbook, 3rd Edn, Wiley, New York (1989)
- Brooks BW, Chem. Eng. Sci., 36, 589 (1981)
- Carratt GM, Shervin CR, Soong DS, Polym. Eng. Sci., 24(6), 442 (1984)
- Choi KY, Polym. Eng. Sci., 26(4), 975 (1986)
- Cunningham MF, O'Driscoll KF, Mahabadi HK, Can. J. Chem. Eng., 69, 630 (1991)
- Hamer JW, Akramov TA, Ray WH, Chem. Eng. Sci., 36, 1897 (1981)
- Hamer JW, Ray WH, Chem. Eng. Sci., 41(12), 3083 (1986)
- Henderson LS, Chem. Eng. Prog., 83(3), 42 (1987)
- Henderson LS, Ind. Eng. Chem. Res., 28, 1644 (1989)
- Hui AW, Hamiele AE, J. Appl. Polym. Sci., 16, 749 (1972)
- Jaisinghani R, Ray WH, Chem. Eng. Sci., 32, 811 (1977)
- Kim KY, Choi KY, Chem. Eng. Sci., 43(4), 965 (1988)
- Kim KY, Alexander JC, Choi KY, Polym. Eng. Sci., 30(5), 279 (1990)
- Knorr RS, O'Driscoll KF, J. Appl. Polym. Sci., 14, 2683 (1970)
- Lynn S, AIChE J., 23(3), 387 (1977)
- Mankin JC, Hudson JL, Chem. Eng. Sci., 41, 2651 (1986)
- Mallikarjun R, Nauman EB, Polym. Proc. Eng., 4(1), 31 (1986)
- Pryor WA, Coco JH, Macromolecules, 3(5), 500 (1970)
- Piirma I, Chou LPH, J. Appl. Polym. Sci., 24, 2051 (1979)
- Schmidt AD, Ray WH, Chem. Eng. Sci., 36, 1401 (1981)
- Schmidt AD, Clinch TA, Ray WH, Chem. Eng. Sci., 39(3), 419 (1984)
- Taylor TW, Reichert KH, J. Appl. Polym. Sci., 30, 227 (1985)
- Thiele R, Ins. Chem. Eng. Symp. Ser., 87, 125 (1984)
- Thiele R, Chem. Eng. Sci., 41(4), 1123 (1986)
- Yoon WJ, Choi KY, Polym. Eng. Sci., 36(1), 65 (1996)
- Yoon WJ, Choi KY, J. Appl. Polym. Sci., 46, 1353 (1992)
- Yoon WJ, Choi KY, Polymer, 33(21), 4582 (1992)