Perovskites are promising catalysts for oxidation reactions Good NO selectivity is reported for the oxidation of ammonia into nitric oxide over LaCoO3 More interestingly over this catalyst very little N2O is produced which makes It a potential candidate for industrial ammonia oxidation In order to further develop perovskite catalysts an understanding of the reaction mechanism is necessary Steady-state TAP and oxygen exchange experiments over LaCoO3 have been carried out A reaction mechanism that describes the product distribution (NO N2O and N-2) as a function of the oxidation degree of the catalyst has been proposed The reaction proceeds by a Mars and Van Krevelen mechanism NO and N2O are formed through parallel routes from ammonia via surface nitroxyl (HNO) species Formation of nitrogen occurs through at least three routes Decomposition of both reaction products NO and N2O leads to N-2 the latter decomposition being the fastest The third route to N-2 consists of the reaction of adsorbed ammonia with short-lived oxygen surface species such as peroxide or superoxide species (C) 2010 Elsevier Inc All rights reserved