AIChE Journal, Vol.56, No.11, 2887-2897, 2010
Transversal Patterns in Three-Dimensional Packed Bed Reactors: Oscillatory Kinetics
Formation of transversal patterns in a 3D cylindrical reactor is studied with a catalytic reactor model in which an exothermic first-order reaction of Arrhenius kinetics occurs with a variable catalytic activity. Under these oscillatory kinetics, the system exhibits a planar front (1D) solution with the front position oscillating in the axial direction. Three types of patterns were simulated in the 3D system: rotating fronts, oscillating fronts with superimposed transversal (nonrotating) oscillations, and mixed rotating-oscillating fronts. These solutions coexist with the planar front solution and require special initial conditions. We map bifurcation diagrams showing domains of different modes using the reactor radius as a bifurcation parameter. The possible reduction of the 3D model to the 2D cylindrical shell model is discussed. (C) 2010 American Institute of Chemical Engineers AIChE J, 56: 2887-2897, 2010