Applied Chemistry, Vol.15, No.1, 29-32, May, 2011
Salicylic Acid 정량을 위한 Europium-Salicylic Acid 복합체의 계면활성제 증감 형광법에 관한 연구
Study of Surfactant Sensitized Fluorescence of Europium-Salicylic Acid Complex for the Determination of Salicylic Acid
Surfactant enhanced fluorescence (FL) of europium-salicylic acid (SA) complex has been studied. It was observed that weak FL of Eu(III) at the wavelength of 589 nm and 612 nm was found to be enhanced after addition of salicylic acid and cetyltrimethylammonium bromide (CTAB) surfactant upon excitation at 395 nm. Under optimized condition, FL intensity of Eu(III) at 612 nm responded linearly with the concentration of SA in the range of 5.5×10^(-9) to 1.5×10^(-6) M of SA. The detection limit was calculated from the calibration curve(3Sb/m) as 9.27×10^(-9)M.