Electrochemical kinetic study of amperometric hydrogen peroxide biosensor fabricated using SBR

Hyon-Seung Dho; Kil-Joong Yoon

Journal of Industrial and Engineering Chemistry, Vol.17, No.2, 254-258, March, 2011

DOI10.1016/j.jiec.2011.02.016 Export Citation

Electrochemical kinetic study of amperometric hydrogen peroxide biosensor fabricated using SBR

Hyon-Seung Dho, and Kil-Joong Yoon^{1, †}

Division of Natural Sciences, Cheongju University, Cheongju 360-764, Republic of Korea
¹Department of Civil and Environmental Engineering, Cheongju University, Cheongju 360-764, Republic of Korea

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When rubber solution was used as a binder of carbon powder, the fast volatility of its solvent, toluene, assured the mechanical solidity of the carbon paste electrode just after electrode fabrication. This utility of the rubber binder met qualifications for the practical use of carbon paste electrodes and heightened morale to design a new enzyme electrode bound with SBR. In an attempt to evaluate the possibilities for practical use of the electrode, its electrochemical kinetic parameters, e.g. the symmetry factor (0.41), the exchange current density (i0, 4.62×10^(-7) A/cm2), the capacitance of double layer (Cd, 8.1×10^(-6) F), the time constant (tA, 0.019 s), the maximum current (imax, 9.80×10^(-5) A/cm2), the Michaelis constant (KM, 4.24×10^(-3) M), the diffusion constant (D1/2, 1.59×10^(-6) cm/s1/2) of the substrate, and other factors were investigated. Results show that SBR is a desirable binder of carbon powder.

Keywords:SBR;Hydrogen peroxide;Peroxidase;Carbon paste electrode;Biosensor;Chicken liver

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[Referenced By]

[1] Cheng TJ, Lin TM, Chang HC, Anal. Chim. Acta., 462, 261 (2002)

[2] Gooding JJ, Pugliano L, Hibbert DB, Erokhin P, Electrochem. Commun., 2, 217 (2000)

[3] Roy JJ, Abraham TE, Abhijith KS, Kumar PVS, Thakur MS, Biosens. Bioelectron., 21, 206 (2005)

[4] Yang YF, Mu SL, Biosens. Bioelectron., 21, 74 (2005)

[5] Vostiar I, Tkac J, Sturdik E, Gemeiner P, Bioelectrochem., 56, 113 (2002)

[6] Miscoria SA, Barrera GD, Rivas GA, Sens. Actuators B., 115, 205 (2006)

[7] Miquel AS, Arben M, Salvador A, Sens. Actuators B., 69, 153 (2000)

[8] Olschewski H, Erlenkotter A, Zaborosch C, Chemnitius GC, Enzyme Microb. Technol., 26(7), 537 (2000)

[9] Chen X, Zhang JZ, Wang BQ, Cheng GJ, Dong SJ, Anal. Chim. Acta., 434, 255 (2001)

[10] Li YC, Bu WF, Wu LX, Sun CQ, Sens. Actuators B., 107, 921 (2005)

[11] Tingry S, Innocent C, Touil S, Deratani A, Seta P, Mater. Sci. Eng. C., 26, 222 (2006)

[12] Morrin A, Guzman A, Killard AJ, Pingarron JM, Smyth MR, Biosens. Bioelectron., 00, 1 (2003)

[13] Wang J, Mo JW, Li SF, Porter J, Anal. Chim. Acta., 441, 183 (2001)

[14] Yoon KJ, Anal. Sci. Technol., 16, 504 (2003)

[15] Yoon KJ, J. Kor, Chem. Soc., 48, 654 (2004)

[16] Choi SY, Yoon KJ, Elastomer., 41, 231 (2006)

[17] Yoon KJ, Anal. Sci. Technol., 20, 49 (2007)

[18] Yoon KJ, Bull. Kor. Chem. Soc., 29, 2264 (2008)

[19] Lee BG, Rhyu KB, Yoon KJ, Bull. Kor. Chem. Soc., 30, 2457 (2009)

[20] Lee BG, Rhyu KB, Yoon KJ, J. Ind. Eng. Chem., 16(3), 340 (2010)

[21] Brydson, Rubbery Materials and Their Compounds, Elsvier Applied Science, London and New York, 99 (1988)

[22] Yoon KJ, Ind. Sci. Res. Ins., CJU, 27, 7 (2009)

[23] Lee BG, Rhyu KB, Yoon KJ, Anal. Sci. Technol., 22, 355 (2009)

[24] Mansouri A, Makris DP, Kefalas P, J. Pharm. Bio. Anal., 39, 22 (2005)

[25] Graft E, Mahoney J, Bryant RG, Eaton W, J. Biol. Chem., 259, 3620 (1984)

[26] Yoon KJ, Bull. Kor. Chem. Soc., 25, 997 (2004)