화학공학소재연구정보센터
Journal of Crystal Growth, Vol.312, No.18, 2499-2502, 2010
Recent achievements in AMMONO-bulk method
In this paper we present progress made recently in the development of the growth of truly bulk GaN crystals by the ammonothermal method in basic environment. High quality 2-in c-plane GaN seeds are shown. Non-polar wafers can also be cut out from thick GaN crystals grown by ammonothermal method. Perfect crystallinity manifests in very narrow peaks in X-ray rocking curves (the full width at half maximum equals about 15 arcsec). GaN epilayers deposited on these substrates exhibit intrinsic narrow exciton lines, which are very sensitive to the optical selection rules typical for hexagonal symmetry, proving the truly non-polar character of such AMMONO-GaN substrates. Other challenges like homogenous insulating properties or high p-type conductivity have been also accomplished by means of ammonothermal method. Semi-insulating crystals of resistivity up to 10(11) Omega cm and p-type conductivity within hole concentration up to 10(18) cm(-3) are already available in diameters up to 1.5-in. (C) 2010 Elsevier B.V. All rights reserved.