Journal of Crystal Growth, Vol.312, No.21, 3122-3126, 2010
Growth of high quality a-plane GaN epi-layer on r-plane sapphire substrates with optimization of multi-buffer layer
Nonpolar (1 1-20) a-plane GaN films have been grown using the multi-buffer layer technique on (1-1 0 2) r-plane sapphire substrates. In order to obtain epitaxial a-plane GaN films, optimized growth condition of the multi-buffer layer was investigated using atomic force microscopy, high resolution X-ray diffraction, and transmission electron microscopy measurements. The experimental results showed that the growth conditions of nucleation layer and three-dimensional growth layer significantly affect the crystal quality of subsequently grown a-plane GaN films. At the optimized growth conditions, omega full-width at half maximum values of (11-20) X-ray rocking curve along c- and m-axes were 430 and 530 arcsec, respectively. From the results of transmission electron microscopy, it was suggested that the high crystal quality of the a-plane GaN film can be obtained from dislocation bending and annihilation by controlling of the island growth mode. (C) 2010 Elsevier B.V. All rights reserved.
Keywords:X-ray diffraction;Metal-organic chemical vapor deposition;Nitrides;Semiconducting III-V materials