In a laboratory study, Portland cement (15%, w/w) was used for solidification/stabilisation (S/S) of Cd, Pb, Zn, Cu, Ni and As contaminated soils from the former industrial site. Soils formed solid monoliths with cement. S/S effectiveness was assessed by measuring the mechanical strength of the monoliths, concentrations of metals in deionised water and TCLP (toxicity characteristic leaching procedure) soil extracts, and mass transfer of metals. Concentrations of Cd, Pb, Zn and Ni in water extracts from S/S soils generally decreased, concentrations of As remained unchanged, while concentrations of Cu increased. Concentrations of Cd. Pb, Zn and Ni in the TCLP extracts from S/S soils were lower than from original soils. Cu extractability was lower in most soil samples, while the extractability of As from S/S soils increased. Overall, the concentration of metals in deionised water and TCLP solution, obtained after extraction of the S/S soils, was below the regulatory limits. S/S greatly reduced the mass transfer of Cd (up to 83-times), Pb (up to 13.7-times) and Zn (up to 294-times). Mass transfer of Ni and As was generally also reduced, while that of Cu increased in some S/S soils. Based on the findings of mass-transfer mechanism analysis the predominant mechanism of release was surface wash-off of metals otherwise physically encapsulated within the cementous soil matrix. (C) 2010 Elsevier B.V. All rights reserved.