The present review aims to give to a researcher who has no experience with Photofuelcells all necessary basic knowledge to join the field without much trouble and to give to an experienced researcher a handy manual of reference. The author has dealt with the principal matters related with the design of a photoelectrochemical cell and the factors that affect efficient production of electricity by photocatalytic degradation of (principally) organic and (secondarily) inorganic waste materials. A large portion of the paper is devoted to the review of materials used for making a photoanode since most of the accomplished research is on this exact matter. The paper also briefly reviews the materials used to make the rest of the components of the cell as well as the models of cell efficiency and photodegradation procedures during cell operation. (C) 2010 Elsevier B.V. All rights reserved.