It is found that the solid solubility of Ce in Nd2-xCeCuO4 +/-delta is limited up to x=0.2. A semiconductor to metallic transition is observed at 600 degrees C in d.c. conductivity data, which coincides with a transition in temperature-dependent area-specific resistance (ASR). Nd1.8Ce0.2CuO4 +/-delta is thermodynamically and chemically stable against gadolinia-doped ceria (GDC) up to 1200 degrees C. On the other hand, it reacts with a yttria-stabilized zirconia electrolyte to form Nd2Zr2O7. At 700 degrees C, the ASR of a Nd1.8Ce0.2CuO4 +/-delta/GDC/Nd1.8Ce0.2CuO4 +/-delta cell sintered at 800 degrees C is 0.13 ohm cm(2), and the ASR proportionally improves with increase in the sintering temperature of the electrochemical cell. The improved ASR and electrochemical performance are attributed to the nanocrystalline nature of the cathode material. (C) 2010 Elsevier B.V. All rights reserved.