Preparation of transparent TS-1 zeolite film and its photocatalytic isomerization under UV irradiation

Jung KT; Shul YG; Anpo M; Yamashita H

Korean Journal of Chemical Engineering, Vol.14, No.3, 213-215, May, 1997

TS-1 zeolite film has been prepared by using nano size TS-1 zeolite particle for the photocatalytic isomerization of cis-2-butene, TS-1 zeolite film showed optical transparent property and the thickness of film was 0.7 μm. UV irradiation of TS-1 zeolite film in the presence of cis-2-butene leads to the photocatalytic isomerization of cis-2-butene into trans-2-butene at the temperature of 275 K. The yield of trans-2-butene was linearly increased with UV-irradiation time.

Keywords:Transparent film;TS-1;Photocatalyst;Geometric isomerization

[References]

Anpo M, Yamada Y, Coluccia S, Zecchina A, Che M, J. Chem. Soc.-Faraday Trans., 85, 609 (1989)
Daganis R, Chem. Eng. News, 23, 18 (1992)
Ichihashi Y, Yamashita H, Ampo H, "The in situ Characterizationof Titanium Oxides Prepared in the Zeolite Cavity, and Frameworks, and Their Photocatalytic Reactivities for Direct Decomposition of NO into N₂ at 275 K," Submitted (1996)
Inui T, Iwamoto S, Kojo S, Yoshida T, Catal. Lett., 16, 223 (1992)
Jung KT, Hyun JH, Kim DS, Shul YG, "Synthesis of Fibrous TS-1 Zeolite," In Proceedings of the 11th International Congress on Catalysis, San Diego (1996)
Jung KT, Shul YG, Accepted Chem. Mater. (1996)
Kiyozumi Y, Shin S, Shul YG, Ihm SK, Koo KK, Korean J. Chem. Eng., 13(2), 144 (1996)
Lee JH, Jung KT, Shul YG, HWAHAK KONGHAK, 34(6), 765 (1996)
Moon SC, Hieida T, yamashita H, Anpo M, Chem. Lett., 447 (1995)
Nizamidin J, Tatsumi T, "Synthesis and Characterization of New Titanium Silico-Aluminophosphate TAPSO-37," Internation Zeolite Conference, Seoul (1996)
Sano T, Kiyozumi Y, Maedea K, Niwa S, Mizukami F, J. Mater. Chem., 2, 141 (1992)
Tsapatsis M, Lovallo M, Okubo T, Davis ME, Sadakata M, J. Chem. Mater., 7, 1734 (1995)
Yan YS, Davis ME, Gavalas GR, Ind. Eng. Chem. Res., 34(5), 1652 (1995)

[Referenced By]

[1] Anpo M, Yamada Y, Coluccia S, Zecchina A, Che M, J. Chem. Soc.-Faraday Trans., 85, 609 (1989)

[2] Daganis R, Chem. Eng. News, 23, 18 (1992)

[3] Ichihashi Y, Yamashita H, Ampo H, "The in situ Characterizationof Titanium Oxides Prepared in the Zeolite Cavity, and Frameworks, and Their Photocatalytic Reactivities for Direct Decomposition of NO into N₂ at 275 K," Submitted (1996)

[4] Inui T, Iwamoto S, Kojo S, Yoshida T, Catal. Lett., 16, 223 (1992)

[5] Jung KT, Hyun JH, Kim DS, Shul YG, "Synthesis of Fibrous TS-1 Zeolite," In Proceedings of the 11th International Congress on Catalysis, San Diego (1996)

[6] Jung KT, Shul YG, Accepted Chem. Mater. (1996)

[7] Kiyozumi Y, Shin S, Shul YG, Ihm SK, Koo KK, Korean J. Chem. Eng., 13(2), 144 (1996)

[8] Lee JH, Jung KT, Shul YG, HWAHAK KONGHAK, 34(6), 765 (1996)

[9] Moon SC, Hieida T, yamashita H, Anpo M, Chem. Lett., 447 (1995)

[10] Nizamidin J, Tatsumi T, "Synthesis and Characterization of New Titanium Silico-Aluminophosphate TAPSO-37," Internation Zeolite Conference, Seoul (1996)

[11] Sano T, Kiyozumi Y, Maedea K, Niwa S, Mizukami F, J. Mater. Chem., 2, 141 (1992)

[12] Tsapatsis M, Lovallo M, Okubo T, Davis ME, Sadakata M, J. Chem. Mater., 7, 1734 (1995)

[13] Yan YS, Davis ME, Gavalas GR, Ind. Eng. Chem. Res., 34(5), 1652 (1995)