The proximities of specific subgroups of nearest-neighbor chains in glassy polymers are revealed by distance-dependent C-13-C-13 dipolar couplings and spin diffusion. The measurement of such proximities is practical even with natural-abundance levels of C-13 using a 2D version of centerband-only detection of exchange (CODEX). Two-dimensional CODEX is a relaxation-compensated experiment that avoids the problems associated with variations in T-1(C)'s due to dynamic site heterogeneity in the glass. Isotropic chemical shifts are encoded in the t(1) preperation times before and after mixing, and variations in T-2's are compensated by an S-0 reference (no mixing). Data acquistion involves acquisition of an S-0 reference signal on alternate scans, and the active control of power amplifiers, to achieve stability and accuracy over long accumulation times. The model system to calibrate spin diffusion is the polymer itself. For a mixing time of 200 ms, only C-13-C-13 pairs separated by one or two bonds (2.5 angstrom) show cross peaks, which therefore identify reference intrachain proximities. For a mixing of 12 ms, 5 angstrom interchain proximities appear. The resulting cross peaks are used in a simple and direct way to compare nonrandom chain packing for two commercial polycarbonates with decidedly different mechanical properties.