Inorganic Chemistry, Vol.34, No.26, 6553-6555, 1995
Crystal-Structure of (LiBr-Center-Dot-Et(2)O)(4) - First Example of a Diethyl Ether-Solvated LiBr Lattice Fragment
The title compound consists of discrete tetramers with heterocubane structures. Each lithium is coordinated to three Br anions and one oxygen of diethyl ether. This enhances the structural variety of inorganic lithium halide complexes.
Keywords:LEWIS-BASE ADDUCTS;GROUP-1 METAL-COMPOUNDS;ORGANO-LITHIUM COMPOUNDS;X = CL;COMPLEXES;BROMIDE;IODIDE;BR;HALIDES;LIGANDS