Surface-enhanced Raman scattering (SERS) probes based on gold nanoparticles modifying the core of the optical fiber were made by a surfactantless photochemical deposition method. The growth kinetics and shape evolution of gold nanoparticles depending on different experimental conditions were studied. It was found that, under the condition of detectable gold nanoparticle deposition, increasing the concentration of chloroauric acid (HAuCl4) was not conducive to the deposition whereas increasing the concentration of sodium citrate (Na(3)Ct) would speed up the deposition : By controlling the concentration of the reaction solution and irradiation time, we obtained fused spherical-like, spherical, and flowerlike gold nanoparticles. TO test the SERS activity of the probes, the SERS spectra of a rhodamine 6G aqueous solution were recorded in direct detection mode and remote mode. We have also developed a new approach to improving the SERS sensitivity when detecting in remote mode.