화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.28, No.6, 1364-1371, June, 2011
DOI10.1007/s11814-010-0528-5  Export Citation
Improved performance of Mo-V-Te-Nb-Ox catalysts prepared from a solution containing drying control chemical additives in propane oxidation to acrylic acid
Sang Seop Kum, Yoon Sik Park, and Sang Heup Moon†
  • School of Chemical & Biological Engineering and Institute of Chemical Processes, Seoul National University, Seoul 151-744, Korea
E-mail:
Mo1.0V0.4Te0.25Nb0.24Ox catalyst was prepared by hydrothermal synthesis in a solution containing a drying control chemical additive (DCCA) such as propionic acid (PA) or formamide (FA). The performance of the prepared catalysts in propane oxidation for producing acrylic acid (AA) was improved because the catalyst showed an increase in both the activity and AA selectivity. The activity was increased due to an increase in the surface area and in the oxygen mobility. The AA selectivity was increased due to a decrease in the number of acidic sites, which were responsible for the unselective and deep oxidation of intermediates. The catalyst performance was degraded when excess amounts of DCCA were used in the preparation step because the surface area decreased, due to the residues of DCCA, and the surface density of acidic sites increased.
Keywords:MoVTeNbOx;Propane Oxidation;Acrylic Acid;Drying Control Chemical Additive
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