Solubility of red pepper (Capsicum annum) oil in nearand supercritical carbon dioxide and quantification of capsaicin

Kyung-Tae Kwon; Md. Salim Uddin; Go-Woon Jung; Jeong-Eun Sim; Seung-Mi Lee; Hee-Chul Woo; Byung-Soo Chun

Korean Journal of Chemical Engineering, Vol.28, No.6, 1433-1438, June, 2011

DOI10.1007/s11814-010-0515-x Export Citation

Solubility of red pepper (Capsicum annum) oil in nearand supercritical carbon dioxide and quantification of capsaicin

Kyung-Tae Kwon, Md. Salim Uddin, Go-Woon Jung, Jeong-Eun Sim, Seung-Mi Lee, Hee-Chul Woo¹, and Byung-Soo Chun^†

Department of Food Science and Technology, Pukyong National University, Busan 608-737, Korea
¹Department of Chemical Engineering, Pukyong National University, Busan 608-737, Korea

E-mail:

Red pepper oil was extracted using near- and supercritical carbon dioxide. Extraction was carried out at pressures ranging from 10 to 35 MPa and temperatures from 30 to 60 oC, with a CO2 flow rate of 24.01 g/min using a semi-continuous high-pressure extraction apparatus. The duration for extraction was 2 h. The highest oil yield was found at high pressure and temperature. The highest solubility of oil (1.18mg/g of CO2) was found at 35 MPa and 60 ℃ . The solubility data of red pepper oil in near- and supercritical CO2 were fitted in Chrastil model. The fatty acid composition of red pepper oil was analyzed by gas chromatography (GC). Linoleic acid was found to be the major fatty acid in the oil. Capsaicin was quantified in different extracts by high performance liquid chromatography (HPLC). The highest capsaicin yield was found at 35 MPa and 60 ℃.

Keywords:Red Pepper Oil;Near- and Supercritical Carbon Dioxide;Capsaicin;Solubility

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[2] Newman AA, Chem. Prod. Chem. News., 16, 413 (1953)

[3] Suzuki T, Iwai K, in The alkaloids: Chemistry and pharmacology, Brossi A, Eds., Academic Press, Orlando, FL, USA, 23, 227 (1984)

[4] Thiele R, Mueller-Seitz E, Petz M, J. Agric. Food Chem., 56, 4219 (2008)

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[8] Majeed M, Badmev V, Prakash L, Natrajan S, Gopinathan S, Capsaicin: The anti-arthritic phytochemical, Nutri. Science Publ. Inc., Piscataway, NJ, USA (1977)

[9] Tominaga M, Chem. Senses., 30, I191 (2005)

[10] Jordt SE, McKemy DD, Julius D, Curr. Opin. Neurobiol., 13, 487 (2003)

[11] Saria A, Lembeck F, Shofitaheh B, J. Chromatogr., 208, 41 (1981)

[12] Krajewska AM, Powers JJ, J. Assoc. Off Anal. Chem., 70, 926 (1987)

[13] Yao J, Nair MG, Chandra A, J. Agric. Food Chem., 42, 1303 (1994)

[14] Sanders N, in Extraction of natural products using near-critical solvents, King MB, Bott TR Eds., Blackie Academic & Professional, London, UK, 34 (1993)

[15] Kang KY, Ahn DH, Wilkinson GT, Chun BS, Korean J. Chem. Eng., 22(3), 399 (2005)

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[18] Yoo KP, Shin HY, Noh MJ, You SS, Korean J. Chem. Eng., 14(5), 341 (1997)

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[21] Corso MP, Fagundes-Klen MR, Silva EA, Cardozo L, Santos JN, Freitas LS, Dariva C, J. Supercrit. Fluids, 52(1), 56 (2010)

[22] Brunner G, Springer, New York, USA (1994)

[23] AOCS, American Oil Chemists’ Society, Champaign, Illinois, USA (1998)

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[25] Morita A, Kajimoto O, J. Phys. Chem., 94, 6420 (1990)

[26] Bai S, Craig MV, Liu LF, Mayne CL, Pugmire RJ, Grant DM, J. Phys. Chem., 101, 2923 (1997)

[27] Bulgarevich DS, Sako T, Sugeta T, Otake K, Takebayashi Y, Kamizawa C, Horikawa Y, Kato M, Ind. Eng. Chem. Res., 41(9), 2074 (2002)

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[29] Sovova H, Zarevucka M, Vacek M, Stransky K, J. Supercrit. Fluids, 20(1), 15 (2001)

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[32] Careri M, Furlattini L, Mangia A, Musci M, Anklam E, Theobald A, Holst CV, J. Chromatogr. A., 912, 61 (2001)

[33] Lopez M, Arce L, Garrido J, Rios A, Valcarcel M, Talanta., 64, 726 (2004)

[34] Chrastil J, J. Phys. Chem., 86, 3016 (1982)

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