Modification and characterization of amberlite XAD-2 with calcein blue for preconcentration and determination of copper(II) from environmental samples by atomic absorption spectroscopy

Elham Moniri; Homayon Ahmad Panahi; Meghdad Karimi; Nasir Ahmad Rajabi; Mohammad Faridi; Mahboobeh Manoochehri

Korean Journal of Chemical Engineering, Vol.28, No.7, 1523-1531, July, 2011

DOI10.1007/s11814-010-0529-4 Export Citation

Modification and characterization of amberlite XAD-2 with calcein blue for preconcentration and determination of copper(II) from environmental samples by atomic absorption spectroscopy

Elham Moniri^†, Homayon Ahmad Panahi¹, Meghdad Karimi¹, Nasir Ahmad Rajabi¹, Mohammad Faridi¹, and Mahboobeh Manoochehri¹

Department of Chemistry, Islamic Azad University, Varamin (Pishva) Branch, Iran
¹Department of Chemistry, Islamic Azad University, Central Tehran Branch, Iran

E-mail:

A chelating resin is produced by coupling a dye calcein blue to Amberlite XAD-2 through an azo spacer. The resulting resin has been characterized by FT-IR, elemental analysis, thermogravimetric analysis (TGA) and scanning electron microscopy (SEM) studied for the preconcentration and determination of trace Cu(II) from solution samples. The optimum pH for adsorption of copper ions was 6. The sorption capacity of functionalized resin is 27 mg·g^(-1). The chelating resin can be reused for 10 cycles without any significant changes in sorption capacity. A recovery of 100% was obtained for Cu(II) when eluted with 0.5M nitric acid. Scatchard analysis revealed that homogeneous binding sites were formed in the resin. The equilibrium adsorption data of Cu(II) on modified resin were analyzed by Langmuir, Freundlich and Temkin models. Based on equilibrium adsorption data the Langmuir, Freundlich and Temkin constants were determined 0.036, 2.196 and 0.348 at pH 6 and 20 ℃, respectively. The method was applied for Cu(II) assay in environmental samples.

Keywords:Copper;Preconcentration;Solid Phase Extraction;Determination;Amberlite XAD-2;Isotherm Study

[References]

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Kaim W, Schwederski B, Bioinorganic chemistry. Inorganic elements in the chemistry of life., John Wiley & Sons, New York (1991)
Praveen RS, Naidu GRK, Rao R, Anal. Chim. Acta., 600, 205 (2007)
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Pehlivan E, Altun T, J. Hazard. Mater., 140(1-2), 299 (2007)
Atanassova A, Dukov IL, Sep. Purif. Technol., 49(1), 101 (2006)
Silva MAM, Frescura VLA, Curtius AJ, Spectrochim. Acta B., 56, 1941 (2001)
Tokalloglu S, Oymak T, Kartal S, Microchim. Acta., 159, 133 (2007)
Ahmad Panahi H, Sid Kalal H, Moniri E, Nikpour Nezhati M, Taheri Menderjani M, Ranjbar Kelahrodi S, Mahmoudi F, Microchem. J., 93, 49 (2009)
Hashemi-Moghaddam H, Ahmad Panahi H, Nikpour Nezhati M, Anal. Lett., 42, 1 (2009)
FeizBakhsh A, Ahmad Panahi H, Nikpour Nezhati M, Water Environ. Res., 81(5), 532 (2009)
Nezhati MN, Panahi HA, Moniri E, Kelahrodi SR, Assadian F, Karimi M, Korean J. Chem. Eng., 27(4), 1269 (2010)
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[2] Kaim W, Schwederski B, Bioinorganic chemistry. Inorganic elements in the chemistry of life., John Wiley & Sons, New York (1991)

[3] Praveen RS, Naidu GRK, Rao R, Anal. Chim. Acta., 600, 205 (2007)

[4] Thomas R, Dulski A, Trace elemental analysis of metals: Methods and techniques., Marcel Dekker Inc., New York (1999)

[5] Pehlivan E, Altun T, J. Hazard. Mater., 140(1-2), 299 (2007)

[6] Atanassova A, Dukov IL, Sep. Purif. Technol., 49(1), 101 (2006)

[7] Silva MAM, Frescura VLA, Curtius AJ, Spectrochim. Acta B., 56, 1941 (2001)

[8] Tokalloglu S, Oymak T, Kartal S, Microchim. Acta., 159, 133 (2007)

[9] Ahmad Panahi H, Sid Kalal H, Moniri E, Nikpour Nezhati M, Taheri Menderjani M, Ranjbar Kelahrodi S, Mahmoudi F, Microchem. J., 93, 49 (2009)

[10] Hashemi-Moghaddam H, Ahmad Panahi H, Nikpour Nezhati M, Anal. Lett., 42, 1 (2009)

[11] FeizBakhsh A, Ahmad Panahi H, Nikpour Nezhati M, Water Environ. Res., 81(5), 532 (2009)

[12] Nezhati MN, Panahi HA, Moniri E, Kelahrodi SR, Assadian F, Karimi M, Korean J. Chem. Eng., 27(4), 1269 (2010)

[13] Ahmad Panahi H, Morshedian J, Mehmandost N, Moniri E, Galaev IY, J. Chromatogr. A., 1217, 5165 (2010)

[14] Ghaedi M, Shokrollahi A, Kianfar AH, Mirsadeghi AS, Pourfarokhi A, Soylak M, J. Hazard. Mater., 154(1-3), 128 (2008)

[15] Ghaedi M, Ahmadi F, Shokrollahi A, J. Hazard. Mater., 142(1-2), 272 (2007)

[16] Ghaedi M, Fathi MR, Marahel F, Ahmadi F, Fresenius Environ. Bull., 14, 1158 (2005)

[17] Ghaedi M, Niknam K, Taheri K, Hossainian H, Soylak M, Food Chem. Toxicol., 48(3), 891 (2010)

[18] Langmuir L, J. Am. Chem. Soc., 40, 1361 (1918)

[19] Hall KL, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng. Chem. Fundam., 5, 212 (1966)

[20] Frendlich HMA, J. Phys. Chem., 57, 385 (1906)

[21] Ho Y, Augustine E, Biochem. Eng. J., 30, 117 (2006)

[22] Somenath Mitra, Sample preparation techniques in analytical chemistry, John Wiley & Sons, New York, 162, 17 (2003)

[23] Feist B, Mikula B, Pytlakowska K, Puzio B, Buhl F, J. Hazard. Mater., 152(3), 1122 (2008)

[24] Umashankar V, Radhamani R, Ramadoss K, Murty DSR, Talanta., 57, 1029 (2002)

[25] Divrikli U, Elci L, Anal. Chim. Acta., 452, 231 (2002)

[26] Soylak M, Saracoglu S, Divrikli U, Elci L, Talanta., 66, 1098 (2005)

[27] Sahin U, Tokahoglu S, Kartal S, Ulgen A, Chem. Anal., 50, 529 (2005)

[28] Ngeontae W, Aeungmaitrepirom W, Tuntulani T, Talanta., 71, 1075 (2007)

[29] Xie F, Lin X, Wu X, Xie Z, Talanta., 74, 836 (2008)

[30] Meesri S, Praphairaksit N, Imyim A, Microchem. J., 87, 47 (2007)

[31] Saracoglu S, Elci L, Anal. Chim. Acta., 452, 77 (2007)

[32] Hirata S, Kajiya T, Takano N, Aihara M, Hondac K, Shikino O, Nakayama E, Anal. Chim. Acta., 499, 157 (2003)

[33] Jankowski K, Yaob J, Kasiura K, Jackowska A, Sieradzka A, Spectrochim. Acta Part B., 60, 369 (2005)

[34] Soylak M, Tuzen M, J. Hazard. Mater., 137(3), 1496 (2006)

[35] Akl MAA, Kenawy IMM, Lasheen RR, Microchem. J., 78, 143 (2004)