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Polymer Bulletin, Vol.65, No.6, 543-550, 2010
Preparation of monodisperse PMMA particles by dispersion polymerization of MMA using poly(styrene-co-methacrylic acid) copolymer as a steric stabilizer
Dispersion polymerization of MMA was conducted using poly(styrene-co-methacrylic acid) copolymer as a steric stabilizer in an aqueous methanol medium. Various composition copolymers were easily prepared with a conventional radical polymerization by changing the monomer ratios of styrene to methacrylic acid, and were employed as a steric stabilizer for dispersion polymerization. The copolymers prepared with monomer ratios of 1.25-1.50 were found to be suitable steric stabilizers for dispersion polymerization. A very small amount of copolymer (0.6 wt% based on MMA) could act as a steric stabilizer effectively to obtain monodisperse PMMA particles. The particle size decreased with increasing the solvent polarity from 4 to 0.14 mu m.
Keywords:Dispersion polymerization;Methyl methacrylate;Poly(styrene-co-methacrylic acid);Monodisperse particles;Steric stabilizer