Separation Science and Technology, Vol.45, No.12-13, 1725-1732, 2010
Lactic Acid Partitioning in TALSPEAK Extraction Systems
The TALSPEAK process, developed in the 1960s at the Oak Ridge National Laboratory and demonstrated in various forms up to pilot scale elsewhere, has emerged as a primary method for partitioning of trivalent transplutonium actinides from fission product lanthanides in advanced nuclear fuel cycles. The baseline process relies on the monoacidic dialkyl phosphoric acid extractant bis-(2-ethylhexyl)phosphoric acid (HDEHP), the aqueous complexant diethylenetriamine-N,N,N',N'',N''-pentaacetic acid (DTPA), and high concentrations of a pH 3.5 buffer, usually 1-2M lactic acid (HL). Previous reports have established that HL not only buffers the pH, but also increases phase transfer kinetics, improves the radiation stability of DTPA, and has been implicated as a possible participant in the formation of ternary complexes in both the aqueous and organic phases. One feature central to the interpretation of these results is the extent of partitioning of HL between the phases. In this study, 14C-labeled HL has been used to examine the details of its partitioning between aqueous solutions and organic solutions relevant to the possible deployment of TALSPEAK. It is found that, contrary to previous reports, HL partitions into the organic phase independently of the amount and identity of the metal ions that are present.