Removal and Recovery of Heavy Metal Ions in Fixed and Semi-Fluidized Beds

Kim SJ; Jeung SY; Moon H

Korean Journal of Chemical Engineering, Vol.15, No.6, 637-643, November, 1998

Uptakes of heavy metal ions such as Pb²⁺ and Ni²⁺ were studied experimentally in fixed and semifluidized beds packed with a strong cation exchange resin, Amberlite 200. Single and binary aqueous solutions of lead and nickel ions were passed through ion exchange columns, and the exit concentrations were measured to get the breakthrough behavior of the ions. From the exit concentration profiles, the breakthrough time and the ion exchange capacity were evaluated. After ;removal of heavy metal ions from binary solution of lead and nickel ions until the breakthrough time, two metal ions were recovered by precipitation and resolubilization of lead. In this paper, the recovery yield and separation efficiency are rigorously discussed.

Keywords:Removal and Recovery;Ion-Exchange;Fixed Bed;Semi-Fluidized Bed;Lead;Nickel

[References]

Anderson RE, "Ion Exchange Separations in Handbook of Separation Technique for Chemical Engineers," Section 1.12, McGraw-Hill, New York (1988)
Clifford D, Ind. Eng. Chem. Fundam., 21, 141 (1982)
Davidson JF, Harrison D, "Fluidization," Academic Press, London, p. 36 (1977)
Fan LT, Yang YC, Wen CY, AIChE J., 6, 482 (1960)
Fan LT, Yang YC, Wen CY, AIChE J., 5, 407 (1959)
Hass CN, Tare V, React. Polym., 2, 61 (1984)
Hwang SJ, Lu WJ, Ind. Eng. Chem. Res., 34(4), 1434 (1995)
Lee K, Hong J, AIChE J., 41(12), 2653 (1995)
Maruyama T, Hannah SA, Cohen JH, Water Pollut. Control Fed. J., 47, 962 (1975)
Patterson JW, "Wastewater Treatment Technology," Ann Arbor Science, Ann Arbor (1975)
Singh AN, Kesavan S, Gupta PS, Int. J. Heat Mass, 23, 279 (1980)

[Referenced By]

[1] Anderson RE, "Ion Exchange Separations in Handbook of Separation Technique for Chemical Engineers," Section 1.12, McGraw-Hill, New York (1988)

[2] Clifford D, Ind. Eng. Chem. Fundam., 21, 141 (1982)

[3] Davidson JF, Harrison D, "Fluidization," Academic Press, London, p. 36 (1977)

[4] Fan LT, Yang YC, Wen CY, AIChE J., 6, 482 (1960)

[5] Fan LT, Yang YC, Wen CY, AIChE J., 5, 407 (1959)

[6] Hass CN, Tare V, React. Polym., 2, 61 (1984)

[7] Hwang SJ, Lu WJ, Ind. Eng. Chem. Res., 34(4), 1434 (1995)

[8] Lee K, Hong J, AIChE J., 41(12), 2653 (1995)

[9] Maruyama T, Hannah SA, Cohen JH, Water Pollut. Control Fed. J., 47, 962 (1975)

[10] Patterson JW, "Wastewater Treatment Technology," Ann Arbor Science, Ann Arbor (1975)

[11] Singh AN, Kesavan S, Gupta PS, Int. J. Heat Mass, 23, 279 (1980)