CeLSCM (CexLa0.75-xSr0.25Cr0.5Mn0.5O3) materials were synthesized for x = 0, 0.10, 0.25 and 0.375. Structural, physico-chemical and electrical properties are compared to La0.75Sr0.25Cr0.5Mn0.5O3 (LSCM). For x <= 0.25. these oxides exhibit a rhombohedral symmetry (space group R 3c), whereas the structure is cubic (Pm-3m) for x = 0.375. All those materials are stable in both elaboration and operating conditions of an SOFC anode. They are also stable in steam electrolysis (SOEC) cathodic conditions. Exposure to air yields the formation of CeO2 for cerium containing materials, and decomposition into a Ruddlesden Popper phase type chromo-manganite occurs in dry H-2 both for CeLSCM series and pure LSCM. In dry argon, wet argon and wet hydrogen, these materials are p-type semi-conductors. Electrical conductivity increases with cerium content in argon and reaches 35 S.cm(-1) at 900 degrees C. In wet hydrogen (H-2-3%H2O), the total conductivity is about 1 S.cm(-1) at 900 degrees C, regardless the cerium content, which is regarded as not so detrimental for the application. (C) 2011 Elsevier B.V. All rights reserved.