화학공학소재연구정보센터
Inorganic Chemistry, Vol.35, No.19, 5622-5626, 1996
Nbxru6-Xte8, New Chevrel-Type Clusters Containing Niobium and Ruthenium
Phases of composition NbxRu6-xTe8 were prepared by reacting stoichiometric mixtures of the elements at high temperature in evacuated silica ampules. The structure of Nb3.33Ru2.67Te8 was refined from X-ray powder data using the Rietveld method Nb3.33Ru2.67Te8 crystallizes isotypic with Mo(6)Q(8) (Q = S, Se, Te) in the rhombohedral space group with the hexagonal lattice parameters a = 10.34106(5) Angstrom, c = 11.47953(7) Angstrom, and Z = 3. Its structure consists of M(6)Te(8) mixed-metal clusters (M = Nb, Ru) which are connected by intercluster M-Te bonds to form a three-dimensional network. Metal-metal bonding in these phases is analyzed in terms of Pauling bond orders and found to be weaker compared to that in related cluster compounds. NbxRu6-xTe8 are the first representatives of Chevrel-type cluster phases with complete substitution of Mo by other metals. The chemical perspectives arising from this substitution are discussed.