Development of Au/La1-xSrxMnO3 nanocomposites for further application in a solid oxide fuel cell type reactor

Wisitsree Wiyaratn; Weerinda Appamana; Suttichai Assabumrungrat

Journal of Industrial and Engineering Chemistry, Vol.17, No.3, 474-478, May, 2011

DOI10.1016/j.jiec.2011.05.025 Export Citation

Development of Au/La1-xSrxMnO3 nanocomposites for further application in a solid oxide fuel cell type reactor

Wisitsree Wiyaratn^†, Weerinda Appamana¹, and Suttichai Assabumrungrat¹

Department of Production Technology and Education, Faculty of Industrial Education and Technology, King Mongkut’s University of Technology Thonburi, Bangkok 10140, Thailand
¹Centre of Excellence in Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand

E-mail:

Au/La1-xSrxMnO3 (x≒ 0.4) was prepared by an ultrasound-driven technique at nanoscale. Physical morphology was characterised using XRD, TEM, BET and SEM-EDS, and its activity was tested in a fixed bed reactor at two different ratios of CH4/O2. A 79.6% CO selectivity and a 54.7% CH4 conversion were obtained at a low CH4/O2 ratio; however, at higher CH4/O2 ratios, the selectivity of C2 became significant. With the presence of Au, the CH4 conversion, H2 yield and C2 and CO selectivity were improved.

Keywords:Au/La1-xSrxMnO3 nanocomposite;C2 hydrocarbon;Synthesis gas

[References]

Michaels JN, Vayenas CG, J. Electrochem. Soc., 131, 2544 (1984)
Ishihara T, Yamada T, Akbay T, Takita Y, Chem. Eng. Sci., 54(10), 1535 (1999)
Cimino S, Landi G, Lisi L, Russo G, Catal. Today, 117(4), 454 (2006)
Wei HJ, Cao Y, Ji WJ, Au CT, Catal. Commun., 9, 2509 (2008)
Pujare NU, Sammells AF, J. Electrochem. Soc., 135, 2544 (1988)
Steele BCH, Heinzel A, Nature (London)., 414, 345 (2001)
Steele BCH, Solid State Ion., 134(1-2), 3 (2000)
Barison S, Battagliarin M, Daolio S, Fabrizio M, Miorin E, Antonucci PL, Candamano S, Modafferi V, Bauer EM, Bellitto C, Righini G, Solid State Ion., 177(39-40), 3473 (2007)
Navarro RM, Alvarez-Galvan MC, Villoria JA, Gonzalez-Jimenez ID, Rosa F, Fierro JLG, Appl. Catal. B: Environ., 73(3-4), 247 (2007)
Muller S, Striebel K, Haas O, Electrochim. Acta, 39(11-12), 1661 (1994)
Wang H, Zhao Z, Liang P, Xu CM, Duan AJ, Jiang GY, Xu J, Liu J, Catal. Lett., 124(1-2), 91 (2008)
Lee ES, J. Ind. Eng. Chem., 14(6), 701 (2008)
Haruta M, Catal. Today, 36(1), 153 (1997)
Haruta M, Yamada N, Kobayashi T, Iijima S, J. Catal., 115, 301 (1989)
Luengnaruemitchai A, Thoa DTK, Osuwan S, Gulari E, Int. J. Hydrogen Energy., 30, 981 (2005)
Shin WS, Jung CR, Han J, Nam SW, Lim TH, Hong SA, Lee HI, J. Ind. Eng. Chem., 10(2), 302 (2004)
Haruta M, Tsubota S, Kobayashi T, Kageyama H, Genet MJ, Delmon B, J. Catal., 144, 175 (1993)
Lee DW, Ryu JH, Jeong DH, Lee HS, Chun KM, Lee KY, J. Ind. Eng. Chem., 9(1), 102 (2003)
Visco AM, Bonato A, Milone C, Galvagno S, React. Kinet. Catal. Lett., 62, 219 (1997)
Waters RD, Weimer JJ, Smith JE, Catal. Lett., 30(1-4), 181 (1995)
Yang HC, Chang FW, Roselin LS, J. Mol. Catal. A-Chem., 276(1-2), 184 (2007)
Gaudon M, Robert CL, Ansart F, Stevens P, Rousset A, Solid State Sci., 4, 125 (2002)
Niu JR, Deng JG, Liu W, Zhang L, Wang GZ, Dai HX, He H, Zi XH, Catal. Today, 126(3-4), 420 (2007)
Daengskul S, Thomas C, Thomas I, Mongkolkachit C, Siri S, Amornkibamrung V, Maensiri S, Nanoscale Res. Lett., 4, 839 (2009)
Sreethawong T, Yoshikawa S, Catal. Commun., 6, 661 (2005)
Chang FW, Yu HY, Roselin LS, Yang HC, Appl. Catal. A: Gen., 290(1-2), 138 (2005)

[Referenced By]

[1] Michaels JN, Vayenas CG, J. Electrochem. Soc., 131, 2544 (1984)

[2] Ishihara T, Yamada T, Akbay T, Takita Y, Chem. Eng. Sci., 54(10), 1535 (1999)

[3] Cimino S, Landi G, Lisi L, Russo G, Catal. Today, 117(4), 454 (2006)

[4] Wei HJ, Cao Y, Ji WJ, Au CT, Catal. Commun., 9, 2509 (2008)

[5] Pujare NU, Sammells AF, J. Electrochem. Soc., 135, 2544 (1988)

[6] Steele BCH, Heinzel A, Nature (London)., 414, 345 (2001)

[7] Steele BCH, Solid State Ion., 134(1-2), 3 (2000)

[8] Barison S, Battagliarin M, Daolio S, Fabrizio M, Miorin E, Antonucci PL, Candamano S, Modafferi V, Bauer EM, Bellitto C, Righini G, Solid State Ion., 177(39-40), 3473 (2007)

[9] Navarro RM, Alvarez-Galvan MC, Villoria JA, Gonzalez-Jimenez ID, Rosa F, Fierro JLG, Appl. Catal. B: Environ., 73(3-4), 247 (2007)

[10] Muller S, Striebel K, Haas O, Electrochim. Acta, 39(11-12), 1661 (1994)

[11] Wang H, Zhao Z, Liang P, Xu CM, Duan AJ, Jiang GY, Xu J, Liu J, Catal. Lett., 124(1-2), 91 (2008)

[12] Lee ES, J. Ind. Eng. Chem., 14(6), 701 (2008)

[13] Haruta M, Catal. Today, 36(1), 153 (1997)

[14] Haruta M, Yamada N, Kobayashi T, Iijima S, J. Catal., 115, 301 (1989)

[15] Luengnaruemitchai A, Thoa DTK, Osuwan S, Gulari E, Int. J. Hydrogen Energy., 30, 981 (2005)

[16] Shin WS, Jung CR, Han J, Nam SW, Lim TH, Hong SA, Lee HI, J. Ind. Eng. Chem., 10(2), 302 (2004)

[17] Haruta M, Tsubota S, Kobayashi T, Kageyama H, Genet MJ, Delmon B, J. Catal., 144, 175 (1993)

[18] Lee DW, Ryu JH, Jeong DH, Lee HS, Chun KM, Lee KY, J. Ind. Eng. Chem., 9(1), 102 (2003)

[19] Visco AM, Bonato A, Milone C, Galvagno S, React. Kinet. Catal. Lett., 62, 219 (1997)

[20] Waters RD, Weimer JJ, Smith JE, Catal. Lett., 30(1-4), 181 (1995)

[21] Yang HC, Chang FW, Roselin LS, J. Mol. Catal. A-Chem., 276(1-2), 184 (2007)

[22] Gaudon M, Robert CL, Ansart F, Stevens P, Rousset A, Solid State Sci., 4, 125 (2002)

[23] Niu JR, Deng JG, Liu W, Zhang L, Wang GZ, Dai HX, He H, Zi XH, Catal. Today, 126(3-4), 420 (2007)

[24] Daengskul S, Thomas C, Thomas I, Mongkolkachit C, Siri S, Amornkibamrung V, Maensiri S, Nanoscale Res. Lett., 4, 839 (2009)

[25] Sreethawong T, Yoshikawa S, Catal. Commun., 6, 661 (2005)

[26] Chang FW, Yu HY, Roselin LS, Yang HC, Appl. Catal. A: Gen., 290(1-2), 138 (2005)